宋华, 武显春, 汪怀远, 等. Promoting Effects of Pt on the Catalytic Performance of Supported NiB Amorphous Alloy Catalysts for Benzene Hydrogenation[J]. 中国化学工程学报(英文版), 2011,19(4):698-702.
SONG Hua, WU Xianchun, WANG Huaiyuan, LI Feng. Promoting Effects of Pt on the Catalytic Performance of Supported NiB Amorphous Alloy Catalysts for Benzene Hydrogenation [J]. , 2011, 19(4): 698-702.
宋华, 武显春, 汪怀远, 等. Promoting Effects of Pt on the Catalytic Performance of Supported NiB Amorphous Alloy Catalysts for Benzene Hydrogenation[J]. 中国化学工程学报(英文版), 2011,19(4):698-702.DOI: 10.1016/S1004-9541(11)60044-X.
SONG Hua, WU Xianchun, WANG Huaiyuan, LI Feng. Promoting Effects of Pt on the Catalytic Performance of Supported NiB Amorphous Alloy Catalysts for Benzene Hydrogenation [J]. , 2011, 19(4): 698-702.DOI: 10.1016/S1004-9541(11)60044-X.
Promoting Effects of Pt on the Catalytic Performance of Supported NiB Amorphous Alloy Catalysts for Benzene Hydrogenation
A support(denoted AM) was prepared using pseudo-boehmite and mordenite.Ni-B and NiPtB amorphous catalysts were prepared on the support by the impregnation method followed by chemical reduction with a KBH4 solution.And the catalysts were characterized by X-ray diffraction(XRD)
environment scanning electron microscope(ESEM)
inductively coupled plasma(ICP)
H
2
-temperature programmed reduction(H
2
-TPR)
differential thermal analysis(DTA)
and BET.Benzene hydrogenation was used as a probe reaction to evaluate the effect of addition of small quantities of Pt on the NiB/AM catalyst.The results show that Pt can promote the reduction of NiO and the formation of active sites
leading to smaller catalyst particles and better dispersion of active metal particles on the support.The catalytic activity
sulfur resistance and thermal stability were remarkably improved by Pt doping of the NiB/AM catalyst.
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相关作者
Qiyao Zhang
Shuangshuang Zhang
Xu Hu
Yongmin Huang
相关机构
Key Laboratory of Specially Functional Polymeric Materials and Related Technology, School of Chemistry and Molecular Engineering, East China University of Science and Technology