王训遒, 庄新亮, 贠莎莎, 等. Measurement and Correlation of Vapor-Liquid Equilibrium for a Cyclohexene-Cyclohexanol Binary System at 101.3 kPa[J]. 中国化学工程学报(英文版), 2011,19(3):484-488.
WANG Xunqiu, ZHUANG Xinliang, YUN Shasha, CHEN Jingbo, JIANG Denggao. Measurement and Correlation of Vapor-Liquid Equilibrium for a Cyclohexene-Cyclohexanol Binary System at 101.3 kPa[J]. , 2011, 19(3): 484-488.
王训遒, 庄新亮, 贠莎莎, 等. Measurement and Correlation of Vapor-Liquid Equilibrium for a Cyclohexene-Cyclohexanol Binary System at 101.3 kPa[J]. 中国化学工程学报(英文版), 2011,19(3):484-488.DOI: 10.1016/S1004-9541(11)60010-4.
WANG Xunqiu, ZHUANG Xinliang, YUN Shasha, CHEN Jingbo, JIANG Denggao. Measurement and Correlation of Vapor-Liquid Equilibrium for a Cyclohexene-Cyclohexanol Binary System at 101.3 kPa[J]. , 2011, 19(3): 484-488.DOI: 10.1016/S1004-9541(11)60010-4.
Measurement and Correlation of Vapor-Liquid Equilibrium for a Cyclohexene-Cyclohexanol Binary System at 101.3 kPa
Many by-products are generated in the process of oxidizing cyclohexene to produce 1
2-epoxycyclohexane by hydrogen peroxide
including cyclohexanol
cyclohexanone
etc
.To obtain high-purity 1
2-epoxycyclohexane
the by-products and unreacted cyclohexene must be removed through rectification
in which the vapor-liquid equilibrium(VLE)data of the system are needed.In this study
the VLE data of cyclohexene-cyclohexanol system were studied at 101.3 kPa using an improved EC-2 VLE still.The thermodynamic consistency of the data was examined by Herington’s method.The results obtained were exemplary.The VLE data were correlated by the Wilson equation. The difference between the calculated values and the experimental data is minor
indicating that the VLE data are suitable for engineering design.
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