Oxidative Degradation of Soda Lignin Assisted by Microwave Irradiation
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Oxidative Degradation of Soda Lignin Assisted by Microwave Irradiation
Oxidative Degradation of Soda Lignin Assisted by Microwave Irradiation
中国化学工程学报(英文版)2010年18卷第4期 页码:695-702
Affiliations:
1. School of Chemistry and Chemical Engineering, South China University of Technology,Guangzhou,China,510640
2. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology,Guangzhou,China,510640
Author bio:
Funds:
Supported by the National Natural Science Foundation of China(20876064);the Natural Science Foundation of Guangdong Province(9151064101000082);the Guangdong Provincial International Cooperation Fund(2008B05010006)
欧阳新平, 林再雄, 邓永红, 等. Oxidative Degradation of Soda Lignin Assisted by Microwave Irradiation[J]. 中国化学工程学报(英文版), 2010,18(4):695-702.
OUYANG Xinping, LIN Zaixiong, DENG Yonghong, YANG Dongjie, QIU Xueqing. Oxidative Degradation of Soda Lignin Assisted by Microwave Irradiation[J]. , 2010, 18(4): 695-702.
欧阳新平, 林再雄, 邓永红, 等. Oxidative Degradation of Soda Lignin Assisted by Microwave Irradiation[J]. 中国化学工程学报(英文版), 2010,18(4):695-702.DOI: 10.1016/S1004-9541(10)60277-7.
OUYANG Xinping, LIN Zaixiong, DENG Yonghong, YANG Dongjie, QIU Xueqing. Oxidative Degradation of Soda Lignin Assisted by Microwave Irradiation[J]. , 2010, 18(4): 695-702.DOI: 10.1016/S1004-9541(10)60277-7.
Oxidative Degradation of Soda Lignin Assisted by Microwave Irradiation
oxidation temperature and time on the degradation of soda lignin by hydrogen peroxide with and without the presence of microwave irradiation were investigated.It is found that the oxidative degradation of lignin includes the cleavage of ether bond in
β-O-
4 structure
the partial destruction of aromatic ring
and the re-condensation of the degraded lignin.Compared to the conventionally heated oxidation of lignin
the microwave irradiation efficiently facilitates the degradation of the lignin with high molecular weight and the re-condensation of that with low molecular weight at a low oxidant dosage
low oxidation temperature
or a short oxidation time
which leads to the formation of the degraded lignin with narrower molecular weight distribution and lower molecular weight.Additionally
the lignin degraded in the presence of microwave irradiation has the characteristics of higher content of phenolic hydroxyl group
lower content of methoxyl group
and lower degree of condensation
which enhances the reactivity of lignin.Therefore
the oxidative degradation of lignin assisted by microwave irradiation may be a new pretreatment approach for efficiently utilizing the soda lignin.
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