Preparation and Characterization of a Novel Polyamide Charged Mosaic Membrane

张景亚; 张延武; 张浩勤; 党敬川; 刘金盾

doi:10.1016/S1004-9541(10)60260-1

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Preparation and Characterization of a Novel Polyamide Charged Mosaic Membrane

Updated：2026-01-06

- Preparation and Characterization of a Novel Polyamide Charged Mosaic Membrane
- Preparation and Characterization of a Novel Polyamide Charged Mosaic Membrane
- 中国化学工程学报（英文版） 2010年18卷第4期页码：569-576
- Affiliations：
  
  1. School of Chemical Engineering, Zhengzhou University,Zhengzhou,China,450001
  2. School of Pharmacy, Henan University of Traditional Chinese Medicine,Zhengzhou,China,450008
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(10)60260-1
  中图分类号：
- 纸质出版：2010
- Accepted：
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张景亚, 张延武, 张浩勤, 等. Preparation and Characterization of a Novel Polyamide Charged Mosaic Membrane[J]. 中国化学工程学报（英文版）, 2010,18(4):569-576.

ZHANG Jingya, ZHANG Yanwu, ZHANG Haoqin, DANG Jingchuan, LIU Jindun. Preparation and Characterization of a Novel Polyamide Charged Mosaic Membrane[J]. Chin.J.Chem.Eng., 2010, 18(4): 569-576.
张景亚, 张延武, 张浩勤, 等. Preparation and Characterization of a Novel Polyamide Charged Mosaic Membrane[J]. 中国化学工程学报（英文版）, 2010,18(4):569-576. DOI： 10.1016/S1004-9541(10)60260-1.

ZHANG Jingya, ZHANG Yanwu, ZHANG Haoqin, DANG Jingchuan, LIU Jindun. Preparation and Characterization of a Novel Polyamide Charged Mosaic Membrane[J]. Chin.J.Chem.Eng., 2010, 18(4): 569-576. DOI： 10.1016/S1004-9541(10)60260-1.

摘要

Abstract

A novel composite charged mosaic membrane (CCMM) was prepared via interfacial polymerization (IP) of polyamine[poly (epichlorohydrin amine)

]

and trimesoyl chloride (TMC) on the polyethersulfone (PES) support. Fourier transform infrared spectroscopy (FT-IR)

environmental scanning electron microscopy (ESEM)

atomic force microscopy (AFM) and water contact angle analysis were applied to characterize the resulted CCMM.The FT-IR spectrum indicates that TMC reacts sufficiently with polyamine.ESEM and AFM pictures show that the IP process produces a dense selective layer on the support membrane.The water contact angle of the CCMM is smaller than that of the substrate membrane because of the cross-linked hydrophilic polyamine network.Several factors affecting the IP reaction and the performance of the CCMM

such as monomer concentration

reaction time

pH value of aqueous phase solution and post-treatment

were studied.The pure water flux of the optimized CCMM is 14.73 L·m

-2

·h

-1

·MPa

-1

at the operating pressure of 0.4 MPa.The values of separation factorαfor NaCl/PEG1000/water and MgC

/PEG1000/water are 11.89 and 9.96

respectively.These results demonstrate that CCMM is promising for the separation of low-molecular-weight organics from their salt aqueous solutions.

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