Preparation and Characterization of Alumina Membranes on Capillary Supports:Effect of Film-coating on Crack-free Membrane Preparation
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Preparation and Characterization of Alumina Membranes on Capillary Supports:Effect of Film-coating on Crack-free Membrane Preparation
Preparation and Characterization of Alumina Membranes on Capillary Supports:Effect of Film-coating on Crack-free Membrane Preparation
中国化学工程学报(英文版)2010年18卷第3期 页码:377-383
Affiliations:
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology,Nanjing,China,210009
Author bio:
Funds:
Supported by the National High Technology Research and Development Program of China(2007AA030303);the National Basic Research Program of China(2009CB623400);the National Natural Science Foundation of China(20776067)
朱瑾, 范益群, 徐南平. Preparation and Characterization of Alumina Membranes on Capillary Supports:Effect of Film-coating on Crack-free Membrane Preparation[J]. 中国化学工程学报(英文版), 2010,18(3):377-383.
ZHU Jin, FAN Yiqun, XU Nanping. Preparation and Characterization of Alumina Membranes on Capillary Supports:Effect of Film-coating on Crack-free Membrane Preparation[J]. , 2010, 18(3): 377-383.
朱瑾, 范益群, 徐南平. Preparation and Characterization of Alumina Membranes on Capillary Supports:Effect of Film-coating on Crack-free Membrane Preparation[J]. 中国化学工程学报(英文版), 2010,18(3):377-383.DOI: 10.1016/S1004-9541(10)60234-0.
ZHU Jin, FAN Yiqun, XU Nanping. Preparation and Characterization of Alumina Membranes on Capillary Supports:Effect of Film-coating on Crack-free Membrane Preparation[J]. , 2010, 18(3): 377-383.DOI: 10.1016/S1004-9541(10)60234-0.
Preparation and Characterization of Alumina Membranes on Capillary Supports:Effect of Film-coating on Crack-free Membrane Preparation
Ceramic capillary membrane has received much attention due to its relatively high pack density and favorable mechanical strength.However
it is difficult to prepare capillary membrane on its thin support by a dip-coating method.In this study
alumina microfiltration membranes were prepared on the inner surface of alumina capillary support(outer diameter 4 mm
inner diameter 2.5 mm)by a dip-coating method.Scanning electron microscopy(SEM)observation
gas bubble pressure(GBP)method and membrane permeation test were carried out to evaluate membrane performance.Two major effects in preparation of crack-free membrane
capillary filtration and film-coating
upon the thin support were studied.The as-prepared crack-free membrane presents a narrow pore size distribution
a mean pore size of about 0.6μm and a high pure water flux of 86000 L·m
-2
·h
-1
·MPa.It is proved that the membrane thickness should be sufficiently large to overcome the defects of support surface
but it is only one of the prerequisites for the formation of crack-free membrane.Furthermore
it is demonstrated that the capillary filtration effect is greatly restricted for thin capillary support with the dip-coating method and the film-coating effect plays a crucial role in the formation of crack-free membrane.
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相关作者
Quanfu An
Naixin Wang
Pei Wu
Zhanquan Zhang
Jie Li
Xiangqiong Wang
Hao Sun
Tong Liu
相关机构
Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemical Engineering, College of Materials Science and Engineering, Beijing University of Technology
Petrochemical Research Institute, CNPC
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University
State Key Laboratory of Materials-Oriented Chemical Engineering, National Engineering Research Center for Special Separation Membranes, College of Chemical Engineering, Nanjing Tech University