Direct Synthesis of Amine-functionalized Mesoporous Silica for CO2 Adsorption
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Direct Synthesis of Amine-functionalized Mesoporous Silica for CO2 Adsorption
Direct Synthesis of Amine-functionalized Mesoporous Silica for CO2 Adsorption
中国化学工程学报(英文版)2011年19卷第3期 页码:386-390
Affiliations:
Chemical Engineering Research Center, State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Tianjin University,Tianjin,China,300072
胡智辉, 张东辉, 王纪孝. Direct Synthesis of Amine-functionalized Mesoporous Silica for CO2 Adsorption[J]. 中国化学工程学报(英文版), 2011,19(3):386-390. DOI: 10.1016/S1004-9541(09)60225-1.
Adsorption[J]. , 2011, 19(3): 386-390.
胡智辉, 张东辉, 王纪孝. Direct Synthesis of Amine-functionalized Mesoporous Silica for CO2 Adsorption[J]. 中国化学工程学报(英文版), 2011,19(3):386-390. DOI: 10.1016/S1004-9541(09)60225-1.DOI:
Amine-functionalized mesoporous silica was prepared by using lauric acid and N-stearoyl-l-glutamic acid as structure directing agents via the S
-
N
+
-I
-
mechanism and applied to CO
2
adsorption at room temperature. With γ-aminopropyltriethoxysilane as co-structure directing agent and due to the direct electrostatic interaction with anionic surfactant
most of the amino groups were uniformly distributed at the inner surface of pores and the performance was stable. The amine-functionalized mesoporous silica was characterized by Fourier transform infrared spectrometer
X-ray diffraction
nitrogen physisorption and thermogravimetric analysis. The CO
2
adsorption capacity was measured by digital recording balance. At the room temperature and under the atmospheric pressure
the adsorption capacity of LAA-AMS-0.2 for CO
2
and N
2
is 1.40 mmol·g
-1
and 0.03 mmol·g
-1
respectively
indicating high separation coefficient of CO
2
/N
2
.
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