Effect of Dissolved Cadmium Chloride and Ammonium Chloride Salts on the Enthalpy of Mixing of the Methanol+Benzene System at 303.15 K

TAMILARASAN Rengasamy; ANAND PRABU Arun; KAP JIN Kim; DHARMENDIRA KUMAR Mahendradas

doi:10.1016/S1004-9541(09)60158-0

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Effect of Dissolved Cadmium Chloride and Ammonium Chloride Salts on the Enthalpy of Mixing of the Methanol+Benzene System at 303.15 K

Updated：2026-01-06

- Effect of Dissolved Cadmium Chloride and Ammonium Chloride Salts on the Enthalpy of Mixing of the Methanol+Benzene System at 303.15 K
- Effect of Dissolved Cadmium Chloride and Ammonium Chloride Salts on the Enthalpy of Mixing of the Methanol+Benzene System at 303.15 K
- 中国化学工程学报（英文版） 2010年18卷第6期页码：995-999
- Affiliations：
  
  1. Department of Chemistry, School of Advanced Sciences, Vellore Institute of Technology University, Vellore,India,632014
  2. Department of Advanced Materials Engineering for Information & Electronics, College of Engineering, Kyung Hee University, Yongin-si, Gyeonggi-do 446-701, South Korea
  3. Department of Chemical Engineering, Alagappa Chettiar College of Technology, Anna University,Chennai,India,600025
- Author bio：
- Funds：
  
  Supported by Basic Science Research Program through the National Research Foundation of Korea(NRF);funded by the Ministry of Education,Science and Technology(R11-2005-065);DST-SERC,New Delhi,India(100/IFD/9726/2009-2010 dated 2/2/2010)
- DOI：10.1016/S1004-9541(09)60158-0
  中图分类号：
- 纸质出版：2010
- Accepted：
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TAMILARASAN Rengasamy, ANAND PRABU Arun, KAP JIN Kim, 等. Effect of Dissolved Cadmium Chloride and Ammonium Chloride Salts on the Enthalpy of Mixing of the Methanol+Benzene System at 303.15 K[J]. 中国化学工程学报（英文版）, 2010,18(6):995-999.

TAMILARASAN Rengasamy, ANAND PRABU Arun, KAP JIN Kim, DHAR-MENDIRA KUMAR Mahendradas. Effect of Dissolved Cadmium Chloride and Ammonium Chloride Salts on the Enthalpy of Mixing of the Methanol+Benzene System at 303.15 K[J]. , 2010, 18(6): 995-999.
TAMILARASAN Rengasamy, ANAND PRABU Arun, KAP JIN Kim, 等. Effect of Dissolved Cadmium Chloride and Ammonium Chloride Salts on the Enthalpy of Mixing of the Methanol+Benzene System at 303.15 K[J]. 中国化学工程学报（英文版）, 2010,18(6):995-999. DOI： 10.1016/S1004-9541(09)60158-0.

TAMILARASAN Rengasamy, ANAND PRABU Arun, KAP JIN Kim, DHAR-MENDIRA KUMAR Mahendradas. Effect of Dissolved Cadmium Chloride and Ammonium Chloride Salts on the Enthalpy of Mixing of the Methanol+Benzene System at 303.15 K[J]. , 2010, 18(6): 995-999. DOI： 10.1016/S1004-9541(09)60158-0.

摘要

Abstract

The effect of two dissolved inorganic salts

cadmium chloride CdCl

and ammonium chloride NH

on the excess enthalpy of mixing(

) of the binary system methanol + benzene measured at 303.15 K using an isothermal displacement calorimeter with vapor space is investigated in the present work. Compared to the salt-free system

a decreasing trend in the endothermicity of

values is significant with the addition of CdCl

salt but the decrease in the

values is insignificantly smaller with the addition of NH

Cl salt. The experimental values of the enthalpy of mixing are fitted into a Redlich-Kister equation and the deviations in the values and the parameters are reported. The importance of the solute-solvent interactions and the solvent-solvent interactions are demonstrated from the increasing excess enthalpy of mixing values in the positive direction with the increase of salt concentration.

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