On-line Measurement for Ohmic Resistance in Direct Methanol Fuel Cell by Current Interruption Method
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On-line Measurement for Ohmic Resistance in Direct Methanol Fuel Cell by Current Interruption Method
On-line Measurement for Ohmic Resistance in Direct Methanol Fuel Cell by Current Interruption Method
中国化学工程学报(英文版)2010年18卷第5期 页码:843-847
Affiliations:
1. College of Chemistry and Chemical Engineering, Central South University,Changsha,China,410083
2. Institute of Nuclear and New Energy Technology, Tsinghua University,Beijing,China,100084
3. Department of Chemical Engineering, University of New Hampshire,NH,USA,03824
Author bio:
Funds:
Supported by the National High Technology Research and Development Program of China (2007AA05Z150);the National Natural Science Foundation of China (50911140287, 50973055)
刘敏, 王金海, 王树博, 等. On-line Measurement for Ohmic Resistance in Direct Methanol Fuel Cell by Current Interruption Method[J]. 中国化学工程学报(英文版), 2010,18(5):843-847.
LIU Min, WANG Jinhai, WANG Shubo, XIE Xiaofeng, ZHOU Tao, V. K. Mathur. On-line Measurement for Ohmic Resistance in Direct Methanol Fuel Cell by Current Interruption Method[J]. , 2010, 18(5): 843-847.
刘敏, 王金海, 王树博, 等. On-line Measurement for Ohmic Resistance in Direct Methanol Fuel Cell by Current Interruption Method[J]. 中国化学工程学报(英文版), 2010,18(5):843-847.DOI: 10.1016/S1004-9541(09)60137-3.
LIU Min, WANG Jinhai, WANG Shubo, XIE Xiaofeng, ZHOU Tao, V. K. Mathur. On-line Measurement for Ohmic Resistance in Direct Methanol Fuel Cell by Current Interruption Method[J]. , 2010, 18(5): 843-847.DOI: 10.1016/S1004-9541(09)60137-3.
On-line Measurement for Ohmic Resistance in Direct Methanol Fuel Cell by Current Interruption Method
Electrochemical impedance spectroscopy (EIS) is widely used in fuel cell impedance analysis. However
for ohmic resistance (
R
Ω
)
EIS has some disadvantages such as long test period and complex data analysis with equivalent circuits. Therefore
the current interruption method is explored to measure the value of
R
Ω
in direct methanol fuel cells (DMFC) at different temperatures and current densities. It is found that
R
Ω
decreases as temperature increase
and decreases initially and then increases as current density increases. These results are consistent with those measured by the EIS technique. In most cases
the ohmic resistances with current interruption (
R
iR
) are larger than those with EIS (
R
EIS
)
but the difference is small
in the range from-0.848% to 5.337%. The errors of
R
iR
at high current densities are less than those of
R
EIS
. Our results show that the
R
iR
data are reliable and easy to obtain in the measurement of ohmic resistance in DMFC.
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