梁蕊, 杨美荣, 轩小鹏. Thermal Stability and Thermal Decomposition Kinetics of 1-Butyl-3-methylimidazolium Dicyanamide[J]. 中国化学工程学报(英文版), 2010,18(5):736-741.
LIANG Rui, YANG Meirong, XUAN Xiaopeng. Thermal Stability and Thermal Decomposition Kinetics of 1-Butyl-3-methylimidazolium Dicyanamide[J]. , 2010, 18(5): 736-741.
梁蕊, 杨美荣, 轩小鹏. Thermal Stability and Thermal Decomposition Kinetics of 1-Butyl-3-methylimidazolium Dicyanamide[J]. 中国化学工程学报(英文版), 2010,18(5):736-741.DOI: 10.1016/S1004-9541(09)60122-1.
LIANG Rui, YANG Meirong, XUAN Xiaopeng. Thermal Stability and Thermal Decomposition Kinetics of 1-Butyl-3-methylimidazolium Dicyanamide[J]. , 2010, 18(5): 736-741.DOI: 10.1016/S1004-9541(09)60122-1.
Thermal Stability and Thermal Decomposition Kinetics of 1-Butyl-3-methylimidazolium Dicyanamide
Thermal stability and thermal decomposition kinetics of 1-butyl-3-methylimidazolium dicyanamide ([bmin
+
]
[N(CN)
]
2
-
) were investigated using both isothermal and non-isothermal thermogravimetric analyses (TGA) under high pure nitrogen as carrier gas. The long-term thermogravimetric studies revealed that the highest temperature used should be 110℃
at which ([bmin
+
]
[N(CN)
]
2
-
) lost less than 10% by mass in 10 hours. The non-isothermal activation energy values determined using Friedman and ASTM methods were (150±13) and (147±2) kJ·mol
-1
respectively. Multivariate non-linear-regression methods showed that expanded Fn and CnB models were the best fit models with highest correlation coefficient of 0.9994
and the apparent activation energies were consistent with iso-conversional methods.
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相关作者
Qi Yabing
Zhao Chumeng
Yuan Tian
Honghua Zhang
Yueyang Qiao
Han Yang
Yanrong Liu
Xiaoyan Ji
相关机构
School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology
CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Mesoscience and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences
Longzihu New Energy Laboratory, Zhengzhou Institute of Emerging Industrial Technology, Henan University
Energy Engineering, Division of Energy Science, Lule? University of Technology, Lule
School of Computer and Software, Shenzhen Institute of Information Technology