Characterization of Tungsten-Based Catalyst Used for Selective Oxidation of Cyclopentene to Glutaraldehyde

朱志庆; 卞炜

doi:10.1016/S1004-9541(09)60013-6

Your Location：

Home >

Browse articles >

Characterization of Tungsten-Based Catalyst Used for Selective Oxidation of Cyclopentene to Glutaraldehyde

Updated：2026-01-06

- Characterization of Tungsten-Based Catalyst Used for Selective Oxidation of Cyclopentene to Glutaraldehyde
- Characterization of Tungsten-Based Catalyst Used for Selective Oxidation of Cyclopentene to Glutaraldehyde
- 中国化学工程学报（英文版） 2008年16卷第6期页码：895-900
- Affiliations：
  
  Institute of Chemical Engineering, East China University of Science and Technology,Shanghai,China,200237
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(09)60013-6
  中图分类号：
- 纸质出版：2008
- Accepted：
Scan QR Code
朱志庆, 卞炜. Characterization of Tungsten-Based Catalyst Used for Selective Oxidation of Cyclopentene to Glutaraldehyde[J]. 中国化学工程学报（英文版）, 2008,16(6):895-900.

ZHU Zhiqing, BIAN Wei. Characterization of Tungsten-Based Catalyst Used for Selective Oxidation of Cyclopentene to Glutaraldehyde[J]. , 2008, 16(6): 895-900.
朱志庆, 卞炜. Characterization of Tungsten-Based Catalyst Used for Selective Oxidation of Cyclopentene to Glutaraldehyde[J]. 中国化学工程学报（英文版）, 2008,16(6):895-900. DOI： 10.1016/S1004-9541(09)60013-6.

ZHU Zhiqing, BIAN Wei. Characterization of Tungsten-Based Catalyst Used for Selective Oxidation of Cyclopentene to Glutaraldehyde[J]. , 2008, 16(6): 895-900. DOI： 10.1016/S1004-9541(09)60013-6.

摘要

Abstract

Tungsten-containing hexagonal mesoporous silica(W-HMS) supported tungsten oxide catalysts (WO

/W-HMS) was prepared for the selective oxidation of cyclopentene with aqueous hydrogen peroxide to glutaraldehyde.X-ray diffraction(XRD) results indicated that the crystal form of the active phase(tungsten oxide) of the WO

/W-HMS catalysts was dependent on the W loading and calcination temperature.X-ray photoelectron spectroscopy(XPS) analysis revealed that the dispersed tungsten oxides on the surface of W-HMS support consisted of a mixture of W(V) and W(VI).It was found that a high content of amorphous W species in(5+)oxidation state resulted in the high catalytic activity.When the Wloading was up to 12%(by mass) or the catalyst precursor was treated at temperature of 623 K

the catalytic activity decreased due to the presence of WO

crystallites and the oxidation of W(V) to W(VI) on the catalyst surface.Furthermore

-temperature-programmed-desorption (NH

-TPD) analysis showed that the effects of W loading and calcination temperature on the acidity of the catalysts were related to the catalytic activity.Ahigh selectivity of 80.2% for glutaraldehyde with a complete conversion of cyclopentene was obtained over 8% WO

/W-HMS catalyst calcined at 573 K after 14 h of reaction.

关键词

Keywords

references

浏览量

2407

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Removal of phenol via regulation of surface hybridization structure of activated carbon catalysts for persulfacte activation

Enhancing corrosion resistance of heat-assisted forming titanium bipolar plate for proton exchange membrane fuel cell through optimized heat treatment

Acid gas combustion in the inverse diffusion flame for increasing flame temperature under low-level oxygen enrichment conditions

Electrocatalytic glucose oxidation activity of Ni/CNT composites based on low-temperature discharge synthesis

Investigation of reaction pathways and kinetics in the gas-phase noncatalytic oxidation of hexafluoropropylene