Clathrate Hydrate Capture of CO2 from Simulated Flue Gas with Cyclopentane/Water Emulsion
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Clathrate Hydrate Capture of CO2 from Simulated Flue Gas with Cyclopentane/Water Emulsion
Clathrate Hydrate Capture of CO2 from Simulated Flue Gas with Cyclopentane/Water Emulsion
中国化学工程学报(英文版)2010年18卷第2期 页码:202-206
Affiliations:
1. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology,Dalian,China,116012
2. Key Laboratory of Enhanced Heat Transfer and Energy Conversation, Ministry of Education, South China University of Technology,Guangzhou,China,510640
Author bio:
Funds:
Supported by the National High Technology Research and Development Program of China (2007AA03Z229);the National Natural Science Foundation of China(20876019)
李士凤, 樊栓狮, 王金渠, 等. Clathrate Hydrate Capture of CO2 from Simulated Flue Gas with Cyclopentane/Water Emulsion[J]. 中国化学工程学报(英文版), 2010,18(2):202-206. DOI: 10.1016/S1004-9541(08)60343-2.
from Simulated Flue Gas with Cyclopentane/Water Emulsion[J]. , 2010, 18(2): 202-206.
李士凤, 樊栓狮, 王金渠, 等. Clathrate Hydrate Capture of CO2 from Simulated Flue Gas with Cyclopentane/Water Emulsion[J]. 中国化学工程学报(英文版), 2010,18(2):202-206. DOI: 10.1016/S1004-9541(08)60343-2.DOI:
by hydrate is one of the attractive technologies for reducing greenhouse effect.The primary challenges are the large energy consumption
low hydrate formation rate and separation efficiency.This work presents a new method for capture of CO
2
from simulated flue gasCO
2
(16.60%
by mole)/N
2
binary mixture by formation of cyclopentane(CP) hydrates at initial temperature of 8.1℃ with the feed pressures from 2.49 to 3.95 MPa.The effect of cyclopentane and cyclopentane/water emulsion on the hydrate formation rate and CO
2
separation efficiency was studied in a 1000 ml stirred reactor.The results showed the hydrate formation rate could be increased remarkably with cyclopentane/water emulsion.CO
2
could be enriched to 43.97%(by mole) and 35.29%(by mole) from simulated flue gas with cyclopentane and cyclopentane/water(O/W) emulsion
respectively
by one stage hydrate separation under low feed pressure.CO
2
separation factor with cyclopentane was 6.18
higher than that with cyclopentane/water emulsion(4.01)
in the range of the feed pressure.The results demonstrated that cyclopentane/water emulsion is a good additive for efficient hydrate capture of CO
2
.
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