Effect of Aminoaromatic Acids as Additives on the Activity and Selectivity of the Platinum-catalyzed Hydrosilylation of Alkenes

白赢; 彭家建; 胡应乾; 厉嘉云; 邱化玉; 来国桥

doi:10.1016/S1004-9541(08)60314-6

Your Location：

Home >

Browse articles >

Effect of Aminoaromatic Acids as Additives on the Activity and Selectivity of the Platinum-catalyzed Hydrosilylation of Alkenes

Updated：2026-01-06

- Effect of Aminoaromatic Acids as Additives on the Activity and Selectivity of the Platinum-catalyzed Hydrosilylation of Alkenes
- Effect of Aminoaromatic Acids as Additives on the Activity and Selectivity of the Platinum-catalyzed Hydrosilylation of Alkenes
- 中国化学工程学报（英文版） 2009年17卷第6期页码：1038-1042
- Affiliations：
  
  Key Laboratory of Organosilicon Chemistry and Material Technology of the Ministry of Education, Hangzhou Normal University,Hangzhou,China,310012
- Author bio：
- Funds：
  
  Supported by the National High Technology Research and Development Program of China (2006AA03A134);Zhejiang Province Program(2008C14041)
- DOI：10.1016/S1004-9541(08)60314-6
  中图分类号：
- 纸质出版：2009
- Accepted：
Scan QR Code
白赢, 彭家建, 胡应乾, 等. Effect of Aminoaromatic Acids as Additives on the Activity and Selectivity of the Platinum-catalyzed Hydrosilylation of Alkenes[J]. 中国化学工程学报（英文版）, 2009,17(6):1038-1042.

BAI Ying, PENG Jiajian, HU Yingqian, LI Jiayun, QIU Huayu, LAI Guoqiao. Effect of Aminoaromatic Acids as Additives on the Activity and Selectivity of the Platinum-catalyzed Hydrosilylation of Alkenes[J]. , 2009, 17(6): 1038-1042.
白赢, 彭家建, 胡应乾, 等. Effect of Aminoaromatic Acids as Additives on the Activity and Selectivity of the Platinum-catalyzed Hydrosilylation of Alkenes[J]. 中国化学工程学报（英文版）, 2009,17(6):1038-1042. DOI： 10.1016/S1004-9541(08)60314-6.

BAI Ying, PENG Jiajian, HU Yingqian, LI Jiayun, QIU Huayu, LAI Guoqiao. Effect of Aminoaromatic Acids as Additives on the Activity and Selectivity of the Platinum-catalyzed Hydrosilylation of Alkenes[J]. , 2009, 17(6): 1038-1042. DOI： 10.1016/S1004-9541(08)60314-6.

摘要

Abstract

A series of aromatic acids has been tested as additives for the platinum-catalyzed hydrosilylation of styrene with triethoxysilane.Both excellent conversion of styrene and selectivity in favor of the

-adduct were achieved using aminobenzoic acids as additive.Moreover

the use of 4-aminobenzoic acid led to significantly superior enhancement in both catalytic activity and selectivity among the tested aminobenzoic acids.Indeed

100% conversion of styrene and 98.4% selectivity in favor of the

-adduct were obtained.Additionally

hydrosilylations of various alkenes with a variety of platinum catalysts have also been tested

and in each case the conversion of substrate and the selectivity of the

-adduct were promoted by using 4-aminobenzoic acid as additive.

关键词

Keywords

references

浏览量

127

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Charge transfer mediator additive facilitates uniform lithium deposition in ester-based electrolytes

PVC Membrane Selective Electrode for Determination of Cadmium(Ⅱ) Ion in Chocolate Samples

Effects of Additives and Coagulant Temperature on Fabrication of High Performance PVDF/Pluronic F127 Blend Hollow Fiber Membranes via Nonsolvent Induced Phase Separation

Functional Polyethylene Glycol with Carboxyl-supported Platinum as an Efficient Catalysis System for the Hydrosilylation of Alkenes

Effect of Additive EDTA on Crystallization Process of Magnesium Hydroxide Precipitation