Influence of A-type Zeolite on Methane Hydrate Formation
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Influence of A-type Zeolite on Methane Hydrate Formation
Influence of A-type Zeolite on Methane Hydrate Formation
中国化学工程学报(英文版)2009年17卷第5期 页码:854-859
Affiliations:
1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences,Guangzhou,China,510640
2. Guangzhou Center for Gas Hydrate Research, Chinese Academy of Sciences,Guangzhou,China,510640
3. Key Laboratory of Renewable Energy and Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences,Guangzhou,China,510640
Author bio:
Funds:
Supported by the National Natural Science Foundation of China (50876107);the National Basic Research Program of China (2009CB219504);NSFC-Guangdong Union Foundation (NSFC-U0733033);CAS Program (KGCX2-YW-805)
The porous medium has an important effect on hydrate formation.In this paper
the formation process and the gas storage capacity of the methane hydrate were investigated with A-type zeolite and Sodium Dodecyl Sulfate (SDS) existing in the system.The results show that A-type zeolite can influence methane hydrate formation.At the temperature of 273.5 K and pressure of 8.3 MPa
the distilled water with A-type zeolite can form methane hydrate with gaseous methane in 12 hours.The formation process of the system with A-type zeolite was quite steady and the amount of A-type zeolite can influence the gas storage capacity significantly.The adding of A-type zeolite with 0.067 g·(g water)
-1
into 2×10
-3
g·g
-1
SDS-water solution can increase the gas storage capacity
and the maximum increase rate was 31%.Simultaneously the promotion effect on hydrate formation of 3A-type zeolite is much more obvious than that of 5A-type zeolite when the water adding amounts are 0.033 g·g
-1
and 0.067 g·g
-1
at the experimental conditions.
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