Investigation of Nitration Processes of <i>iso</i>-Octanol with Mixed Acid in a Microreactor

沈佳妮; 赵玉潮; 陈光文; 袁权

doi:10.1016/S1004-9541(08)60225-6

Your Location：

Home >

Browse articles >

Investigation of Nitration Processes of iso-Octanol with Mixed Acid in a Microreactor

Updated：2026-01-06

- Investigation of Nitration Processes of iso-Octanol with Mixed Acid in a Microreactor
- Investigation of Nitration Processes of iso-Octanol with Mixed Acid in a Microreactor
- 中国化学工程学报（英文版） 2009年17卷第3期页码：412-418
- Affiliations：
  
  1. Dalian National Laboratory for Clean Energy,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian,China,116023
  2. Graduate University, Chinese Academy of Sciences,Beijing,China,100049
- Author bio：
- Funds：
  
  Supported by the National Natural Science Foundation of China (20490208);the National High Technology Research and Development Program of China (2007AA030206);the Open Fund of State Key Laboratory of Explosion Science and Technology, BIT (KFJJ06-1)
- DOI：10.1016/S1004-9541(08)60225-6
  中图分类号：
- 纸质出版：2009
- Accepted：
Scan QR Code
沈佳妮, 赵玉潮, 陈光文, 等. Investigation of Nitration Processes of iso-Octanol with Mixed Acid in a Microreactor[J]. 中国化学工程学报（英文版）, 2009,17(3):412-418. DOI: 10.1016/S1004-9541(08)60225-6.

-Octanol with Mixed Acid in a Microreactor[J]. , 2009, 17(3): 412-418.
沈佳妮, 赵玉潮, 陈光文, 等. Investigation of Nitration Processes of iso-Octanol with Mixed Acid in a Microreactor[J]. 中国化学工程学报（英文版）, 2009,17(3):412-418. DOI: 10.1016/S1004-9541(08)60225-6. DOI：

-Octanol with Mixed Acid in a Microreactor[J]. , 2009, 17(3): 412-418. DOI： 10.1016/S1004-9541(08)60225-6.

摘要

Abstract

In this paper

the nitration characteristic of alcohols with mixed acid for the synthesis of energetic materials in a stainless steel microreactor was investigated experimentally. The nitration of

iso

-octanol with HNO

-H

mixed acid was chosen as a typical model reaction which involved fast and strong exothermic liquid-liquid heterogeneous reaction process. The influences of mixed acid composition

flow rate

organic/aqueous flow ratio and reaction temperature have been investigated. The results indicated that the reaction could be conducted safely and stably in the microreactor at 25-40℃

which are enhanced compared to 15℃ or below for safe operating conditions in the conventional reactors. Moreover

the 98.2% conversion of

iso

-octanol could be obtained and no by-products were detected in all cases.

关键词

Keywords

references

浏览量

223

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Process Characteristics of CO2 Absorption by Aqueous Monoethanolamine in a Microchannel Reactor

Particle-scale mass transfer characteristics of composite microspheres for cesium ion adsorption in nuclear wastewater within microchannel adsorbers

Bubble breakup in viscous liquids at a microfluidic T-junction

Numerical study on the hydrodynamics behavior of a central insert microchannel

Study on liquid–liquid two-phase mass transfer characteristics in the microchannel with deformed insert

Investigation of Nitration Processes of iso-Octanol with Mixed Acid in a Microreactor

Investigation of Nitration Processes of iso-Octanol with Mixed Acid in a Microreactor

DOI：10.1016/S1004-9541(08)60225-6

摘要

Abstract

关键词

Keywords

references