The robust design of PMIA braided tube reinforced PFA hollow fiber membranes with graphene doping for water-in-oil separation
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The robust design of PMIA braided tube reinforced PFA hollow fiber membranes with graphene doping for water-in-oil separation
The robust design of PMIA braided tube reinforced PFA hollow fiber membranes with graphene doping for water-in-oil separation
中国化学工程学报(英文版)2024年76卷第12期 页码:105-117
Affiliations:
1. School of Materials Science and Engineering, and State Key Laboratory of Separation Membranes and Membrane Processes, Tiangong University,Tianjin,China,300387
2. CAS Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences,Beijing,China,100190
3. Fiber Materials Research Center, School of Textiles and Fashion, Shanghai University of Engineering Science,Shanghai,China,201620
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纸质出版:2024
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Wei Zhao, Xin Jin, Kaikai Chen, 等. The robust design of PMIA braided tube reinforced PFA hollow fiber membranes with graphene doping for water-in-oil separation[J]. 中国化学工程学报(英文版), 2024,76(12):105-117.
Wei Zhao, Xin Jin, Kaikai Chen, Haoyang Ling, Hailiang Liu, Changfa Xiao. The robust design of PMIA braided tube reinforced PFA hollow fiber membranes with graphene doping for water-in-oil separation[J]. Chinese Journal of Chemical Engineering, 2024, 76(12): 105-117.
Wei Zhao, Xin Jin, Kaikai Chen, 等. The robust design of PMIA braided tube reinforced PFA hollow fiber membranes with graphene doping for water-in-oil separation[J]. 中国化学工程学报(英文版), 2024,76(12):105-117.DOI:
Wei Zhao, Xin Jin, Kaikai Chen, Haoyang Ling, Hailiang Liu, Changfa Xiao. The robust design of PMIA braided tube reinforced PFA hollow fiber membranes with graphene doping for water-in-oil separation[J]. Chinese Journal of Chemical Engineering, 2024, 76(12): 105-117.DOI:
The robust design of PMIA braided tube reinforced PFA hollow fiber membranes with graphene doping for water-in-oil separation
-perfluoropropyl vinyl ether) (PFA) hollow fiber membrane with thermal and solvent resistant property was prepared
via
no-solvent green method. The membrane surface and pore structure was optimized by changing the sintering temperature and graphene (GE) content. The morphologies showed that the spherical surface with good lipophilicity was formed
and the excellent mechanical strength with a favorable interface bonding state could be obtained due to the PFA melts permeating into the supporting layer. The doping of GE produced synergistic effects with the sintering temperature owing to its good thermal conductivity and pore formation. The PBR-PFA/GE hollow fiber membrane exhibited good hydrophobicity and lipophilicity with more than 97% separation efficiency for different oil products at -0.02 MPa. With the addition of GE
the average pore size first increases and then decreases
and the porosity gradually decreases. In addition
the hollow fiber membrane showed high separation ability to the water-in-oil emulsion
and maintained a stable flux recovery rate after recycling
making it possible to apply in the field of oily wastewater treatment.
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