The preparation of SnS2@NxC electrodes and its exceptional performance in energy storage usages
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The preparation of SnS2@NxC electrodes and its exceptional performance in energy storage usages
The preparation of SnS2@NxC electrodes and its exceptional performance in energy storage usages
中国化学工程学报(英文版)2024年76卷第12期 页码:75-82
Affiliations:
1. School of Materials Science and Engineering, Jiangsu University of Science and Technology,Zhenjiang,China,21000
2. School of Engineering, University of Waikato, Hamilton 3216, New Zealand
Author bio:
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DOI:
中图分类号:
纸质出版:2024
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Zhen He, Yuqian Wei, Yunfei Song, 等. The preparation of SnS2@NxC electrodes and its exceptional performance in energy storage usages[J]. 中国化学工程学报(英文版), 2024,76(12):75-82.
@NxC electrodes and its exceptional performance in energy storage usages[J]. 中国化学工程学报, 2024, 76(12): 75-82.
Zhen He, Yuqian Wei, Yunfei Song, 等. The preparation of SnS2@NxC electrodes and its exceptional performance in energy storage usages[J]. 中国化学工程学报(英文版), 2024,76(12):75-82.DOI:
@NxC electrodes and its exceptional performance in energy storage usages[J]. 中国化学工程学报, 2024, 76(12): 75-82.DOI:
The preparation of SnS2@NxC electrodes and its exceptional performance in energy storage usages
) anodes have garnered significant attention within emerging energy storage technologies. However
the application of SnS
2
is curtailed due to its inherent limitations
including poor cyclic stability and inevitable volumetric expansion upon cycling. This study reports the successful fabrication of an innovative SnS
2
-based composite
featuring an eggshell-like structured nitrogen-doped carbon coating
referred to as SnS
2
@NxC. This novel architecture
wherein SnS
2
acts as the core encapsulated by a nitrogen-doped carbon shell
characterized by a void space between the shell and core
is crucial in mitigating volumetric expansion. This configuration contributes to maintaining the structural integrity of the composite materials
even under the stresses of continuous cycling. Nitrogen within the carbon matrix enhances conductivity and promotes the formation of a more robust and stable solid electrolyte interphase (SEI) layer. Experimental investigations have substantiated the electrochemical superiority of the SnS
2
@NxC electrode
demonstrating a specific capacity of 701.8 mA·h·g
-1
after 1000 cycles at 0.5 A·g
-1
and maintaining a capacity of 597.2 mA·h·g
-1
after 400 cycles at a heightened current density of 2 A·g
-1
. These findings underscore the exceptional cyclic performance and durability of the SnS
2
@NxC electrode.
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相关作者
Honglai Liu
Cheng Lian
Jianglong Du
Yiting Lin
Wenqi Yang
Haichao Lv
Jindong Dai
Chi Zhai
相关机构
State Key Laboratory of Chemical Engineering and Low-Carbon Technology, School of Chemical Engineering, East China University of Science and Technology
School of Mechanical and Power Engineering, East China University of Science and Technology
State Key Laboratory of Chemical Engineering and Low-Caron Technology, School of Chemistry and Molecular Engineering, East China University of Science and Technology
College of Chemical Engineering, Beijing University of Chemical Technology
Faculty of Chemical Engineering, Kunming University of Science and Technology