Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance
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Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance
Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance
中国化学工程学报(英文版)2024年67卷第3期 页码:68-77
Affiliations:
1. School of Chemical Engineering, Changchun University of Technology,Changchun,China,130012
2. Advanced Institute of Materials Science, Changchun University of Technology,Changchun,China,130012
3. Key Laboratory of Advanced Functional Polymer Membrane Materials of Jilin Province,Changchun,China,130012
4. School of Chemistry and Life Science, Changchun University of Technology,Changchun,China,130012
Author bio:
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DOI:
中图分类号:
纸质出版:2024
Accepted:
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Yi Zhang, Di Liu, Zhaoli Wang, 等. Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance[J]. 中国化学工程学报(英文版), 2024,67(3):68-77.
Yi Zhang, Di Liu, Zhaoli Wang, Junjian Yu, Yanyin Cheng, Wenjing Li, Zhe Wang, Hongzhe Ni, Yuchao Wang. Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance[J]. Chinese Journal of Chemical Engineering, 2024, 67(3): 68-77.
Yi Zhang, Di Liu, Zhaoli Wang, 等. Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance[J]. 中国化学工程学报(英文版), 2024,67(3):68-77.DOI:
Yi Zhang, Di Liu, Zhaoli Wang, Junjian Yu, Yanyin Cheng, Wenjing Li, Zhe Wang, Hongzhe Ni, Yuchao Wang. Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance[J]. Chinese Journal of Chemical Engineering, 2024, 67(3): 68-77.DOI:
Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance
For the reduction of bovine serum proteins from wastewater
a novel mixed matrix membrane was prepared by functionalizing the substrate material polyaryletherketone (PAEK)
followed by carboxyl groups (C-SPAEKS)
and then adding amino-functionalized UiO-66-NH
2
(Am-UiO-66-NH
2
). Aminofunctionalization of UiO-66 was accomplished by melamine
followed by an amidation reaction to immobilize Am-UiO-66-NH
2
which was immobilized on the surface of the membrane as well as in the pore channels
which enhanced the hydrophilicity of the membrane surface while increasing the negative potential of the membrane surface. This nanoparticle-loaded ultrafiltration membrane has good permeation performance
with a pure water flux of up to 482.3 L·
m-2
·
h-1
for C-SPAEKS/AmUiO-66-NH
2
and a retention rate of up to 98.7% for bovine serum albumin (BSA)-contaminated solutions. Meanwhile
after several hydrophilic modifications
the flux recovery of BSA contaminants by this series of membranes increased from 56.2% to 80.55% of pure membranes. The results of ultrafiltration flux time tests performed at room temperature showed that the series of ultrafiltration membranes remained relatively stable over a test time of 300 min. Thus
the newly developed mixed matrix membrane showed potential for high efficiency and stability in wastewater treatment containing bovine serum proteins.
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相关作者
Jianmin Xing
Maohua Yang
Qinhong Wang
Yanjie Ji
Mengxin Liu
Jiachang Shen
Zhengxin Mao
Xiaolong Han
相关机构
CAS, Key Laboratory of Low Carbon Synthetic Engineering Biology, Tianjin Institute of Industrial Biotechnology
Tianjin Juno Biotechnology Company
College of Chemical Engineering, University of Chinese Academy of Sciences
CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences
School of Chemistry and Life Science, Advanced Institute of Materials Science, Changchun University of Technology