Metal-organic-framework-derived copper-based catalyst for multicomponent C-S coupling reaction

Lixin Chen; Hui Zhang; Linxi Hou; Xin Ge

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Metal-organic-framework-derived copper-based catalyst for multicomponent C-S coupling reaction

Updated：2026-01-06

- Metal-organic-framework-derived copper-based catalyst for multicomponent C-S coupling reaction
- Metal-organic-framework-derived copper-based catalyst for multicomponent C-S coupling reaction
- 中国化学工程学报（英文版） 2024年70卷第6期页码：1-8
- Affiliations：
  
  1. Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University,Wuxi,China,214122
  2. Department of Materials-Oriented Chemical Engineering, School of Chemical Engineering, Fuzhou University,Fuzhou,China,350116
  3. Qingyuan Innovation Laboratory,Quanzhou,China,362801
- Author bio：
- Funds：
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  中图分类号：
- 纸质出版：2024
- Accepted：
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Lixin Chen, Hui Zhang, Linxi Hou, 等. Metal-organic-framework-derived copper-based catalyst for multicomponent C-S coupling reaction[J]. 中国化学工程学报（英文版）, 2024,70(6):1-8.

Lixin Chen, Hui Zhang, Linxi Hou, Xin Ge. Metal-organic-framework-derived copper-based catalyst for multicomponent C-S coupling reaction[J]. Chinese Journal of Chemical Engineering, 2024, 70(6): 1-8.
Lixin Chen, Hui Zhang, Linxi Hou, 等. Metal-organic-framework-derived copper-based catalyst for multicomponent C-S coupling reaction[J]. 中国化学工程学报（英文版）, 2024,70(6):1-8. DOI：

Lixin Chen, Hui Zhang, Linxi Hou, Xin Ge. Metal-organic-framework-derived copper-based catalyst for multicomponent C-S coupling reaction[J]. Chinese Journal of Chemical Engineering, 2024, 70(6): 1-8. DOI：

摘要

Abstract

Copper-based metal-organic frameworks (Cu-MOFs) are a promising multiphase catalyst for catalyzing C-S coupling reactions by virtue of their diverse structures and functions. However

the unpleasant odor and instability of the organosulfur

as well as the mass-transfer resistance that exists in multiphase catalysis

have often limited the catalytic application of Cu-MOFs in C-S coupling reactions. In this paper

a Cu-MOFs catalyst modified by cetyltrimethylammonium bromide (CTAB) was designed to enhance mass transfer by increasing the adsorption of organic substrates using the long alkanes of CTAB. Concurrently

elemental sulfur was used to replace organosulfur to achieve a highly efficient and atom-economical multicomponent C-S coupling reaction.

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