Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study
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Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study
Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study
中国化学工程学报(英文版)2023年60卷第8期 页码:212-227
Affiliations:
1. College of Chemistry and Chemical Engineering, Chongqing University,Chongqing,China,400044
Lingli Chen, Yueting Shi, Sijun Xu, 等. Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study[J]. 中国化学工程学报(英文版), 2023,60(8):212-227.
Lingli Chen, Yueting Shi, Sijun Xu, Junle Xiong, Fang Gao, Shengtao Zhang, Hongru Li. Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study[J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 212-227.
Lingli Chen, Yueting Shi, Sijun Xu, 等. Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study[J]. 中国化学工程学报(英文版), 2023,60(8):212-227.DOI:
Lingli Chen, Yueting Shi, Sijun Xu, Junle Xiong, Fang Gao, Shengtao Zhang, Hongru Li. Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study[J]. Chinese Journal of Chemical Engineering, 2023, 60(8): 212-227.DOI:
Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study
an approach was proposed to employ new target branched compounds (TBCs) including multiple antibiotic norfloxacin frameworks for intensified adsorption films to achieve super protection of mild steel in HCl medium. Thus
the TBCs containing bis/tri norfloxacin skeletons were synthesized by multi-step preparation route. In addition
the reference linear compound (RLC) including a single norfloxacin part was also synthesized. The chemical structures of these compounds were confirmed by various means. It was demonstrated that the TBCs could form the tough adsorption films on the surface of mild steel
which could be processed mainly through chemisorption effect. The electrochemical analysis suggested that the TBCs displayed superior corrosion inhibition performance for low carbon steel in 1.0 mol·L
-1
HCl solution over the RLC (RLC
87.80%; TBC1
97.63%; TBC2
98.35%)
which was further understood by the molecular modelling. The isotherm adsorption plots were employed to analyze the spontaneous adsorption process of the TBCs on low carbon steel surface
and a prominent chemisorption could be inferred by the stan
dard Gibbs free energy changes of the adsorption.
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相关作者
Guo Yan
Hou Tuanyuan
Wang Yongjin
Chang Liping
Wang Jiancheng
Liao Junjie
Lu Tangzheng
Feng Jiayi
相关机构
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology
College of Chemistry and Chemical Engineering, Xinjiang Normal University
Key Laboratory of Coal Science and Technology, Ministry of Education, Taiyuan University of Technology
College of Chemistry and Chemical Engineering, Taiyuan University of Technology
School of Chemical Engineering and Technology, Tianjin University