Measurement and model of density, viscosity, and hydrogen sulfide solubility in ferric chloride/trioctylmethylammonium chloride ionic liquid
Full Length Article|Updated:2026-01-06
|
Measurement and model of density, viscosity, and hydrogen sulfide solubility in ferric chloride/trioctylmethylammonium chloride ionic liquid
Measurement and model of density, viscosity, and hydrogen sulfide solubility in ferric chloride/trioctylmethylammonium chloride ionic liquid
中国化学工程学报(英文版)2023年59卷第7期 页码:210-221
Affiliations:
College of Chemical Engineering, Qingdao University of Science and Technology,Qingdao,China,266042
Author bio:
Funds:
DOI:
中图分类号:
纸质出版:2023
Accepted:
Scan QR Code
Zhonghao Li, Yuanyuan Yang, Huanong Cheng, 等. Measurement and model of density, viscosity, and hydrogen sulfide solubility in ferric chloride/trioctylmethylammonium chloride ionic liquid[J]. 中国化学工程学报(英文版), 2023,59(7):210-221.
Zhonghao Li, Yuanyuan Yang, Huanong Cheng, Yun Teng, Chao Li, Kangkang Li, Zhou Feng, Hongwei Jin, Xinshun Tan, Shiqing Zheng. Measurement and model of density, viscosity, and hydrogen sulfide solubility in ferric chloride/trioctylmethylammonium chloride ionic liquid[J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 210-221.
Zhonghao Li, Yuanyuan Yang, Huanong Cheng, 等. Measurement and model of density, viscosity, and hydrogen sulfide solubility in ferric chloride/trioctylmethylammonium chloride ionic liquid[J]. 中国化学工程学报(英文版), 2023,59(7):210-221.DOI:
Zhonghao Li, Yuanyuan Yang, Huanong Cheng, Yun Teng, Chao Li, Kangkang Li, Zhou Feng, Hongwei Jin, Xinshun Tan, Shiqing Zheng. Measurement and model of density, viscosity, and hydrogen sulfide solubility in ferric chloride/trioctylmethylammonium chloride ionic liquid[J]. Chinese Journal of Chemical Engineering, 2023, 59(7): 210-221.DOI:
Measurement and model of density, viscosity, and hydrogen sulfide solubility in ferric chloride/trioctylmethylammonium chloride ionic liquid
The density and viscosity of ferric chloride/trioctylmethylammonium chloride ionic liquid (
r
FeCl
3
/[A336
]
Cl) with different molar ratios (
r
= 0.1-0.8) of FeCl
3
to [A336
]
Cl were measured at temperatures from 313.15 to 358.15 K and atmospheric pressure. The density and viscosity data were fitted by the relevant temperature variation equations
respectively. The variation of density and viscosity with temperature and
r
was obtained. The solubility of
r
FeCl
3
/[A336
]
Cl to H
2
S was measured at temperatures from 318.15 to 348.15 K and pressures from 0 to 150 kPa. The effects of temperature
pressure
and
r
on the solubility of H
2
S were discussed. The reaction equilibrium thermodynamic model (RETM) was used to fit the H
2
S solubility data
and the average relative error was less than 1.3%
indicating that the model can relate the solubility data well. And Henry's constant and chemical reaction equilibrium constant were obtained by the RETM fitting. The relationships of Henry's constant and chemical reaction equilibrium constant with temperature and
r
were analyzed.
关键词
Keywords
references
The trial reading is over, you can activate your VIP account to continue reading.
Absorption characteristics, model, and molecular mechanism of hydrogen sulfide in morpholine acetate aqueous solution
Prediction of ionic liquid toxicity by interpretable machine learning
Solubility determination and comparison of β-HMX and RDX in two binary mixed solvents (acetonitrile + water, nitric acid + water)
Viscous behavior of 1-hexyl-methylimidazolium bis(trifluoromethylsulfonyl)imide/titanium dioxide/polyethylene glycol
Efficient conversion of H2S into mercaptan alcohol by tertiary-amine functionalized ionic liquids
相关作者
Shiqi Qu
Hongzhi Xia
Yugang Li
Haijun Feng
Li Jiajia
Zhou Jian
Yuehua Yao
Fan Wang
相关机构
School of Computer and Software, Shenzhen Institute of Information Technology
School of Chemistry and Chemical Engineering, Guangdong Provincial Key Laboratory for Green Chemical Product Technology, South China University of Technology
School of Chemistry and Chemical Engineering, North University of China
Gansu Yinguang Chemical Industry Group Co. Ltd.
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University