Uniform deposition of ultra-thin TiO2 film on mica substrate by atmospheric pressure chemical vapor deposition: Effect of precursor concentration
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Uniform deposition of ultra-thin TiO2 film on mica substrate by atmospheric pressure chemical vapor deposition: Effect of precursor concentration
Uniform deposition of ultra-thin TiO2 film on mica substrate by atmospheric pressure chemical vapor deposition: Effect of precursor concentration
中国化学工程学报(英文版)2023年60卷第8期 页码:99-107
Affiliations:
1. State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences,Beijing,China,100190
2. School of Chemical & Environmental Engineering, China University of Mining and Technology-, Beijing,Beijing,China,100083
3. School of Chemical Engineering, University of Chinese Academy of Sciences,Beijing,China,100049
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纸质出版:2023
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Ming Liu, Ying Li, Rui Wang, 等. Uniform deposition of ultra-thin TiO2 film on mica substrate by atmospheric pressure chemical vapor deposition: Effect of precursor concentration[J]. 中国化学工程学报(英文版), 2023,60(8):99-107.
film on mica substrate by atmospheric pressure chemical vapor deposition: Effect of precursor concentration[J]. 中国化学工程学报, 2023, 60(8): 99-107.
Ming Liu, Ying Li, Rui Wang, 等. Uniform deposition of ultra-thin TiO2 film on mica substrate by atmospheric pressure chemical vapor deposition: Effect of precursor concentration[J]. 中国化学工程学报(英文版), 2023,60(8):99-107.DOI:
film on mica substrate by atmospheric pressure chemical vapor deposition: Effect of precursor concentration[J]. 中国化学工程学报, 2023, 60(8): 99-107.DOI:
Uniform deposition of ultra-thin TiO2 film on mica substrate by atmospheric pressure chemical vapor deposition: Effect of precursor concentration
The performance of pearlescent pigment significantly affected by the grain size and the roughness of deposited film. The effect of TiCl
4
concentration on the initial deposition of TiO
2
on mica by atmospheric pressure chemical vapor deposition (APCVD) was investigated. The precursor concentration significantly affected the deposition and morphology of TiO
2
grains assembling the film. The deposition time for fully covering the surface of mica decreased from 120 to 10 s as the TiCl
4
concentration increased from 0.38% to 2.44%. The grain size increased with the TiCl
4
concentration. The AFM and TEM analysis demonstrated that the aggregation of TiO
2
clusters at the initial stage finally result to the agglomeration of fine TiO
2
grains at high TiCl
4
concentrations. Following the results
it was suggested that the nucleation density and size was easy to be adjusted when the TiCl
4
concentration is below 0.90%.
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