Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine

Tinghao Jia; Yunbo Yu; Qing Liu; Yao Yang; Ji-Jun Zou; Xiangwen Zhang; Lun Pan

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Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine

Full Length Article | Updated：2026-01-06

- Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine
- Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine
- 中国化学工程学报（英文版） 2023年56卷第4期页码：225-232
- Affiliations：
  
  1. Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University,Hangzhou,China,310027
  2. ZJU-Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University,Hangzhou,China,311200
  3. Key Laboratory for Green Chemical Technology of the Ministry of Education, School of Chemical Engineering and Technology, Tianjin University,Tianjin,China,300072
  4. Haihe Laboratory of Sustainable Chemical Transformations,Tianjin,China,300192
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：2023
- Accepted：
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Tinghao Jia, Yunbo Yu, Qing Liu, 等. Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine[J]. 中国化学工程学报（英文版）, 2023,56(4):225-232.

Tinghao Jia, Yunbo Yu, Qing Liu, Yao Yang, Ji-Jun Zou, Xiangwen Zhang, Lun Pan. Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine[J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 225-232.
Tinghao Jia, Yunbo Yu, Qing Liu, 等. Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine[J]. 中国化学工程学报（英文版）, 2023,56(4):225-232. DOI：

Tinghao Jia, Yunbo Yu, Qing Liu, Yao Yang, Ji-Jun Zou, Xiangwen Zhang, Lun Pan. Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine[J]. Chinese Journal of Chemical Engineering, 2023, 56(4): 225-232. DOI：

摘要

Abstract

Antioxidants addition is believed as a facile and effective way to improve jet fuel thermal oxidation stability. However

amine antioxidants

as one of the most important antioxidants

have not received sufficient attention in the field of jet fuel autoxidation yet. Herein

the inhibition efficiency and mechanism of decane and

exo-

tetrahydrodicyclopentadiene (THDCPD) oxidation by di-4-

tert

-butylphenylamine (diarylamine) was experimentally and theoretically investigated. The results show that diarylamine can significantly inhibit decane oxidation but is less efficient for THDCPD oxidation

which is attributed to the higher energy barrier of retro-carbonyl-ene reaction (rate-determining step) in THDCPD than that in decane during diarylamine regeneration. However

the addition of diarylamine will cause undesirable color change after accelerated oxidation and produce slightly more deposits during high-temperature thermal oxidative stress for both decane and THDCPD. The results provide significant implications for the future design of effective antioxidant additives for high-performance jet fuel.

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