Bio-capped and green synthesis of ZnO/g-C3N4 nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation
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Bio-capped and green synthesis of ZnO/g-C3N4 nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation
Bio-capped and green synthesis of ZnO/g-C3N4 nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation
中国化学工程学报(英文版)2023年56卷第4期 页码:215-224
Affiliations:
1. School of Environmental & Chemical Engineering, Jiangsu University of Science and Technology,Zhenjiang,China,212100
2. College of Agriculture, Shihezi University,Shihezi,China,832003
3. Key Laboratory of Biology and Genetic Improvement of Horticultural Crops, Northeast Agricultural University,Harbin,China,150030
4. Jiangxi Key Laboratory for Postharvest Technology and Nondestructive Testing of Fruits and Vegetables, College of Agronomy, Jiangxi Agricultural University,Nanchang,China,330045
5. Department of Pharmacy, University of Swabi, Khyber Pakhtunkhwa,Pakistan,94640
6. Department of Physics, University of Agriculture Faisalabad,Faisalabad,Pakistan,38040
7. Department of Chemistry, Government College University Faisalabad,Faisalabad,Pakistan,38000
Author bio:
Funds:
DOI:
中图分类号:
纸质出版:2023
Accepted:
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Iltaf Khan, Chunjuan Wang, Shoaib Khan, 等. Bio-capped and green synthesis of ZnO/g-C3N4 nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation[J]. 中国化学工程学报(英文版), 2023,56(4):215-224.
N
Iltaf Khan, Chunjuan Wang, Shoaib Khan, 等. Bio-capped and green synthesis of ZnO/g-C3N4 nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation[J]. 中国化学工程学报(英文版), 2023,56(4):215-224.DOI:
NDOI:
Bio-capped and green synthesis of ZnO/g-C3N4 nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation
摘要
Abstract
In this research study
we have synthesized the bio-capped ZnO/g-C
3
N
4
nanocomposites by employing lemon juice (
Citrus limon
) as a stabilizer and mediator. Fruitfully
lemon juice which contains various acidic functional groups and citric acid has the capability to block the surface of g-C
3
N
4
from chemical reactivity and activated the surface of g-C
3
N
4
for various reactions. Consequently
the agglomeration behavior and controlled shape of g-C
3
N
4
has also been achieved. Our experimental results
i.e.
XRD
TEM
HRTEM
PL
FS
XPS
and PEC have confirmed that the lemon juice mediated and green g-C
3
N
4
(L-CN) have good performances and remarkable visible light photocatalytic activities as compared to the chemically synthesized g-C
3
N
4
(CN). Furthermore
the small surface area and low charge separation of g-C
3
N
4
is upgraded by coupling with ZnO nanoparticles. It is proved that the coupling of ZnO worked as a facilitator and photoelectron modulator to enhance the cha
rge separation of g-C
3
N
4
. Compared to pristine lemon-mediated green g-C
3
N
4
(L-CN)
the most active sample 5ZnO/L-CN showed ~ 5-fold improvement in activities for ciprofloxacin (CIP) and methylene blue (MB) degradation. More specifically
the mineralization process and degradation pathways
and the mineralization process of ciprofloxacin (CIP) and methylene blue (MB) are suggested. Finally
our present novel research work will provide new access to synthesize the eco-friendly and bio-caped green g-C
3
N
4
nanomaterials and their employment for pollutants degradation and environmental purification.
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