Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures

Zhiwei Wang; Yu Zhang; Zhi Zhang; Daowei Zhou; Zhikai Cao; Yong Sha

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Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures

Full Length Article | Updated：2026-01-06

- Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures
- Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures
- 中国化学工程学报（英文版） 2023年53卷第1期页码：63-72
- Affiliations：
  
  Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University,Xiamen,China,361005
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：2023
- Accepted：
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Zhiwei Wang, Yu Zhang, Zhi Zhang, 等. Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures[J]. 中国化学工程学报（英文版）, 2023,53(1):63-72.

Zhiwei Wang, Yu Zhang, Zhi Zhang, Daowei Zhou, Zhikai Cao, Yong Sha. Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures[J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 63-72.
Zhiwei Wang, Yu Zhang, Zhi Zhang, 等. Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures[J]. 中国化学工程学报（英文版）, 2023,53(1):63-72. DOI：

Zhiwei Wang, Yu Zhang, Zhi Zhang, Daowei Zhou, Zhikai Cao, Yong Sha. Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures[J]. Chinese Journal of Chemical Engineering, 2023, 53(1): 63-72. DOI：

摘要

Abstract

The catalytic packing is the core component of the catalytic distillation

and how the catalyst exists in the packing has significant influence on the process. To investigate the effect of catalyst packings on the catalytic distillation process

the classical ethyl acetate reactive distillation system was utilized

and a supported catalytic packing (SCP) was prepared in comparison with the conventional tea-bag catalytic packing (TBP). Laboratory scale experiments showed that the ethyl acetate conversion of the SCP was superior to the TBP at a low catalyst loading. The effects of reaction kinetics

mass transfer performance and actual catalytic efficiency of the packings on this process were regarded as reasons and studied by combining the experiments and numerical simulation. Results suggested that the relatively immediate “

in-situ

separation” caused by the rapid reaction kinetics and better mass transfer performance of SCP may be a main reason for the difference of the conversion.

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