Cross-metathesis of biomass to olefins: Molecular catalysis bridging the gap between fossil and bio-energy

Wenjuan Yan; Zhenchao You; Kexin Meng; Feng Du; Shuxia Zhang; Xin Jin

Your Location：

Home >

Browse articles >

Cross-metathesis of biomass to olefins: Molecular catalysis bridging the gap between fossil and bio-energy

Updated：2026-01-06

- Cross-metathesis of biomass to olefins: Molecular catalysis bridging the gap between fossil and bio-energy
- Cross-metathesis of biomass to olefins: Molecular catalysis bridging the gap between fossil and bio-energy
- 中国化学工程学报（英文版） 2022年48卷第8期页码：44-60
- Affiliations：
  
  State Key Laboratory of Heavy Oil Processing, Center for Chemical Engineering Experimental Teaching, China University of Petroleum,Qingdao,China,266580
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：2022
- Accepted：
Scan QR Code
Wenjuan Yan, Zhenchao You, Kexin Meng, 等. Cross-metathesis of biomass to olefins: Molecular catalysis bridging the gap between fossil and bio-energy[J]. 中国化学工程学报（英文版）, 2022,48(8):44-60.

Wenjuan Yan, Zhenchao You, Kexin Meng, Feng Du, Shuxia Zhang, Xin Jin. Cross-metathesis of biomass to olefins: Molecular catalysis bridging the gap between fossil and bio-energy[J]. Chinese Journal of Chemical Engineering, 2022, 48(8): 44-60.
Wenjuan Yan, Zhenchao You, Kexin Meng, 等. Cross-metathesis of biomass to olefins: Molecular catalysis bridging the gap between fossil and bio-energy[J]. 中国化学工程学报（英文版）, 2022,48(8):44-60. DOI：

Wenjuan Yan, Zhenchao You, Kexin Meng, Feng Du, Shuxia Zhang, Xin Jin. Cross-metathesis of biomass to olefins: Molecular catalysis bridging the gap between fossil and bio-energy[J]. Chinese Journal of Chemical Engineering, 2022, 48(8): 44-60. DOI：

摘要

Abstract

Terminal olefins are important building blocks for the industry of biofuels

oligomers

and lubricants production. The industrial processes for production of olefins involving oligomerizationofethylene or cracking of petrochemical waxes have several flaws including low yield and high cost in product separation. Cross-metathesis of bio-derived unsaturated fatty esters and olefins with ethylene (ethenolysis)

allows the conversion of sustainable waste biomass to various renewable olefins with much safer

less toxic

sustainable

and zero-CO

emission processes. To our best knowledge

however

a comprehensive summary of key advances in this field (since 2017) is yet to be available

particularly on molecular features of homogeneous and heterogeneous catalysts. This paper presents a critical review on molecular structures of metal complex and oxide catalysts for ethenolysis of olefins and oleochemicals. The influence of cationic centers

coordination conditions

nature of ligands

operating conditions on catalyst performances will be systematically discussed along with relevant reaction mechanism. The key challenges for rational design of coordinated cationic hybrids have been summarized

which will provide insights to technological advancement of large-scale production of oleochemical-derived olefins.

关键词

Keywords

references

浏览量

283

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Preparation and extrusion of ZSM-5 based on biomass templates for enhanced mechanical properties and catalytic pyrolysis performance

Research progress on catalysts for organic sulfur hydrolysis: Review of activity and stability

Facile preparation of Fe-Beta zeolite-supported transition metal oxide catalysts and their catalytic performance for the simultaneous removal of NOx and soot

An efficient bifunctional Ni-Nb2O5 nanocatalysts for the hydrodeoxygenation of anisole

Spatial-five coordination promotes the high efficiency of CoN4 moiety in graphene-based bilayer for oxygen reduction electrocatalysis: A density functional theory study