To improve performance of membrane electrode assembly (MEA) at large current density region

efficient mass transfer at the cathode is desired

for which a feasible strategy is to lower catalyst layer thickness by constructing high loading Pt-alloy catalysts on carbon. But the high loading may induce unwanted particle aggregation. In this work

H-PtNi/C with 33% (mass) Pt loading on carbon and monodisperse distribution of 3.55?nm PtNi nanoparticles

was prepared by a bimodal-pore route. In electrocatalytic oxygen reduction reaction (ORR)

H-PtNi/C displays an activity inferior to the low Pt loading catalyst L-PtNi/C (13.3% (mass)) in the half-cell. While in H

2

-O

2

MEA

H-PtNi/C delivers the peak power density of 1.51?W·cm

?2

and the mass transfer limiting current density of 4.4?A·cm

?2

being 21% and 16% higher than those of L-PtNi/C (1.25?W·cm

?2

3.8?A·cm

?2

) respectively

which can be ascribed to enhanced mass transfer brought by the thinner catalyst layer in the former. In addition

the same method can be used to prepare PtFe alloy catalyst with a high-Pt loading of 36% (mass). This work may lead to a range of catalyst materials for the large current density applications

such as fuel cell vehicles.