Conjugated microporous polymer (CMP) is an emerging organic semiconductor with p-conjugated skeletons

and the bandgap of CMP can be flexibly modulated to harvest visible light. Based on the diversity and adjustability of monomers in CMP

we designed and synthesized donor-accepter (D-A) type BTNCMP through Sonogashira-Hagihara cross-coupling polymerization

further

in-situ

constructing series of inorganic/organic Z-scheme BW/BTN-

n

composite in the presence of Bi

2

WO

6

. After optimization

the tetracycline hydrochloride (

C

0

= 10 mg·L

-1

) degradation efficiency reached 84% with BW/BTN-2 as catalyst in 90 min under visible light irradiation

the apparent rate constant

k

1

is 0.017 min

-1

which is 1.7 and 5.7 times higher than bare Bi

2

WO

6

and BTN-CMP. X-ray photoelectron spectra and UV–Vis diffuse spectra showed that the enhanced photocatalytic activity originated from the tight heterojunction between Bi

2

WO

6

and BTN-CMP

which can extend the light absorption range and facilitate the separation and transport of photogen

erated charges in the interface of heterojunction. The active species trapping experiments and electron spin resonance technique revealed that

h

+

was the dominant active species during the photodegradation process of tetracycline hydrochloride (TCH). The present study demonstrated the feasibility to construct inorganic/organic composite for the photocatalytic degradation of environmental pollutants.