Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance

Tao Zhao; Dazhong Zhong; Genyan Hao; Guang Liu; Jinping Li; Qiang Zhao

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Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance

Energy Science and Technology | Updated：2026-01-06

- Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance
- Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance
- 中国化学工程学报（英文版） 2022年41卷第1期页码：480-487
- Affiliations：
  
  Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, College of Chemistry and Chemical Engineering, Taiyuan University of Technology,Taiyuan,China,030024
- Author bio：
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  中图分类号：
- 纸质出版：2022
- Accepted：
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Tao Zhao, Dazhong Zhong, Genyan Hao, 等. Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance[J]. 中国化学工程学报（英文版）, 2022,41(1):480-487.

Tao Zhao, Dazhong Zhong, Genyan Hao, Guang Liu, Jinping Li, Qiang Zhao. Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance[J]. Chinese Journal of Chemical Engineering, 2022, 41(1): 480-487.
Tao Zhao, Dazhong Zhong, Genyan Hao, 等. Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance[J]. 中国化学工程学报（英文版）, 2022,41(1):480-487. DOI：

Tao Zhao, Dazhong Zhong, Genyan Hao, Guang Liu, Jinping Li, Qiang Zhao. Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance[J]. Chinese Journal of Chemical Engineering, 2022, 41(1): 480-487. DOI：

摘要

Abstract

Metal-organic frameworks (MOFs) exhibit excellent application potential in the field of electrocatalysis. In this study

we first prepare MIL-100 nanosheets on nickel foam (MIL-100/NF) and then successfully anchor Ag nanoparticles (NPs) on the nanosheets (Ag@MIL-100/NF) for oxygen evolution reaction (OER) catalysis. This strategy dramatically improves the conductivity of MIL-100 and the Ag NPs are uniformly dispersed on the nanosheets. The Ag@MIL-100/NF catalyst has excellent electrocatalytic performance and long-term corrosion resistance

with a low overpotential of 207 mV and a long-term stability of at least 100 h at a current density of 50 mA·cm

-2

. The experimental results demonstrate that this high OER catalytic performance is due to the improved charge transfer after loading Ag NPs

the combination of nanosheets and highly dispersed Ag NPs that expose more active sites and the adjusted chemical valence states of Fe and Ni in MIL-100. This work provides a surface decoration approach for the preparation of excellent catalysts directly used in the OER.

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