O3 based advanced oxidation for ibuprofen degradation
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O3 based advanced oxidation for ibuprofen degradation
O3 based advanced oxidation for ibuprofen degradation
中国化学工程学报(英文版)2022年42卷第2期 页码:277-284
Affiliations:
Laboratory of Separation and Reaction Engineering-Laboratory of Catalysis and Materials, (LSRE-LCM), Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias,Porto,Portugal,4200-465
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纸质出版:2022
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Vitória M. Almeida, Carla A. Orge, M. Fernando R. Pereira, 等. O3 based advanced oxidation for ibuprofen degradation[J]. 中国化学工程学报(英文版), 2022,42(2):277-284.
based advanced oxidation for ibuprofen degradation[J]. 中国化学工程学报, 2022, 42(2): 277-284.
Vitória M. Almeida, Carla A. Orge, M. Fernando R. Pereira, 等. O3 based advanced oxidation for ibuprofen degradation[J]. 中国化学工程学报(英文版), 2022,42(2):277-284.DOI:
based advanced oxidation for ibuprofen degradation[J]. 中国化学工程学报, 2022, 42(2): 277-284.DOI:
O3 based advanced oxidation for ibuprofen degradation
The degradation of the anti-inflammatory ibuprofen (IBP) was evaluated by several advanced oxidation processes. IBP was treated by single ozonation and oxidation with hydrogen peroxide (H
2
O
2
)
as well as a combination of these treatments. In order to improve the efficiency
the presence of catalysts such as original carbon nanotubes
labelled as CNT
and iron oxide supported on carbon nanotubes
named as Fe/CNT sample
was considered. The evolution of IBP degradation
mineralization and toxicity of the solutions was assessed. The formation of intermediates was also monitored. In the non-catalytic processes
IBP was faster removed by single ozonation
whereas no significant total organic carbon (TOC) removal was achieved. Oxidation with H
2
O
2
did not present satisfactory results. When ozone and H
2
O
2
were combined
a higher mineralization was attained (70% after 180 min of reaction). On the other hand
in the catalytic processes
this combined process allowed the fastest IBP degradation. In terms of mineralization degree
the presence of Fe/CNT increases the removal rate in the first hour of reaction
achieving a TOC removal of 85%. Four compounds were detected as by-products. All treated solutions presented lower
toxicity than the initial solution
suggesting that the released intermediates during applied processes are less toxic.
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Ju Shangguan
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