The effect of protic ionic liquids incorporation on CO2 separation performance of Pebax-based membranes
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The effect of protic ionic liquids incorporation on CO2 separation performance of Pebax-based membranes
The effect of protic ionic liquids incorporation on CO2 separation performance of Pebax-based membranes
中国化学工程学报(英文版)2022年43卷第3期 页码:169-176
Affiliations:
1. CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex Systems, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences,Beijing,China,100190
2. School of Future Technology, University of Chinese Academy of Sciences,Beijing,China,100049
3. Advanced Energy Science and Technology Guangdong Laboratory,Huizhou,China,516003
Author bio:
Funds:
DOI:
中图分类号:
纸质出版:2022
Accepted:
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Haiyan Jiang, Lu Bai, Bingbing Yang, 等. The effect of protic ionic liquids incorporation on CO2 separation performance of Pebax-based membranes[J]. 中国化学工程学报(英文版), 2022,43(3):169-176.
separation performance of Pebax-based membranes[J]. 中国化学工程学报, 2022, 43(3): 169-176.
Haiyan Jiang, Lu Bai, Bingbing Yang, 等. The effect of protic ionic liquids incorporation on CO2 separation performance of Pebax-based membranes[J]. 中国化学工程学报(英文版), 2022,43(3):169-176.DOI:
separation performance of Pebax-based membranes[J]. 中国化学工程学报, 2022, 43(3): 169-176.DOI:
The effect of protic ionic liquids incorporation on CO2 separation performance of Pebax-based membranes
) is of great importance for environment protection and gas resource purification. The ionic liquids (ILs)-based gas separation membrane provides a new chance for efficient CO
2
separation
while high permeability and selectivity of membranes is a great challenge. In this study
the influence of two protic ILs with different anion ([TMGH
]
[Im
]
and [TMGH
]
[PhO
]
) on the CO
2
separation performance of the prepared ILs/Pebax blended membranes were systematically investigated at different temperature. The results showed the CO
2
permeability exhibits the rising trend for ILs/Pebax blended membranes with the increment of IL content. Especially
the [TMGH
]
[Im
]
with low viscosity and high CO
2
absorption capacity leads to the blended membranes showing better CO
2
permeability and ideal CO
2
selectivity than that of membranes with [TMGH
]
[PhO
]
at high IL content. Besides
with operating temperature increasing
the gas permeability of 20% (mass) [TMGH
]
[Im
]
/Pebax blended membrane increases due to the decreasing viscosity of IL and the rising chain mobility of polymer. Inversely
the gas selectivity shows decreasing trend because CO
2
absorption capacity obviously decreased at higher temperature.
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