Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution

Mohammad Saood Manzar; Shamsuddeen A. Haladu; Mukarram Zubair; Nuhu Dalhat Mu'azu; Aleem Qureshi; Nawaf I. Blaisi; Thomas F. Garrison; Othman Charles S. Al Hamouz

Your Location：

Home >

Browse articles >

Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution

Energy, Resources and Environmental Technology | Updated：2026-01-06

- Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution
- Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution
- 中国化学工程学报（英文版） 2021年32卷第4期页码：341-352
- Affiliations：
  
  1. Department of Environmental Engineering, Imam Abdulrahman Bin Faisal University, Dammam, Saudi Arabia
  2. Department of Basic Engineering Sciences, Imam Abdulrahman Bin Faisal University, Dammam, Saudi Arabia
  3. Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：2021
- Accepted：
Scan QR Code
Mohammad Saood Manzar, Shamsuddeen A. Haladu, Mukarram Zubair, 等. Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution[J]. 中国化学工程学报（英文版）, 2021,32(4):341-352.

Mohammad Saood Manzar, Shamsuddeen A. Haladu, Mukarram Zubair, Nuhu Dalhat Mu'azu, Aleem Qureshi, Nawaf I. Blaisi, Thomas F. Garrison, Othman Charles S. Al Hamouz. Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution[J]. Chinese Journal of Chemical Engineering, 2021, 32(4): 341-352.
Mohammad Saood Manzar, Shamsuddeen A. Haladu, Mukarram Zubair, 等. Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution[J]. 中国化学工程学报（英文版）, 2021,32(4):341-352. DOI：

Mohammad Saood Manzar, Shamsuddeen A. Haladu, Mukarram Zubair, Nuhu Dalhat Mu'azu, Aleem Qureshi, Nawaf I. Blaisi, Thomas F. Garrison, Othman Charles S. Al Hamouz. Synthesis and characterization of a series of cross-linked polyamines for removal of Erichrome Black T from aqueous solution[J]. Chinese Journal of Chemical Engineering, 2021, 32(4): 341-352. DOI：

摘要

Abstract

A new series of polymers comprising four terpolymers was synthesized via Mannich polycondensation of benzene-1

4-diamine

formaldehyde and piperazine by varying the benzene-1

4-diamine and piperazine ratio. The new polyamines (labeled Dipip) were characterized using

C solid-state NMR

FT-IR

TGA

DSC

XRD

SEM and EDX. The adsorptive performances of the synthesized polymers for Erichrome Black T (EBT) uptake from aqueous solution were investigated under batch process. Equilibrium

kinetic

and thermodynamic studies were conducted to determine the influence of different operational parameters of the adsorption process. The two most promising polymers among the series show an excellent EBT removal efficiency of ~100% and ~95% with high adsorption capacities of 775 mg·g

-1

and 917 mg·g

-1

respectively at a meager dosage of 5 mg. The sorption of EBT on the polymers was well described by Redlich-Peterson Langmuir model while the kinetic studies indicate that pseudo-second order model was followed. For the thermodynamic studies

the negative DG and positive DH values obtained suggest a spontaneity of the sorption

process which was endothermic in nature. The results of reusability test of the resins were promising even at the fourth cycle

showcasing the potentials of the new polymers in dyes contaminated water treatment.

关键词

Keywords

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Adsorption Behavior of Rhodamine B on UiO-66

A closed-loop strategy for ciprofloxacin adsorption and degradation by acetic acid/H2O2modified biochar

Mechanisms and reusability potentials of zirconium-polyaziridine-engineered tiger nut residue towards anionic pollutants

A green cross-linking method for the preparation of renewable three-dimensional graphene sponges for efficient adsorption of Congo red dye

Unraveling structure and performance of protein a ligands at liquid–solid interfaces: A multi-techniques analysis