Electrocoagulation (EC) is among the most effective techniques that remove color and decontaminate effluent. Coagulants are delivered

in situ

by anode corrosion. In this research

indigo dye removal using iron electrodes in continuous electrocoagulation process and the responsible species for decolorization were investigated. The Response Surface Methodology (RSM) was used to optimize the process parameters. The finding in this study shows that at fixed conductivity at 15

000 μS·cm

-1

the neutral conditions (pH from 6 to 8)

the low absorbance

the low flow rate and the high voltage level enhance the color removal efficiency. The high

R

2

value of 97.8% and ANOVA analyses show a good correlation between the experimental and predicted results. Under the optimum conditions

which are pH of 7.5

solution concentration of 60 mg·L

-1

inlet flow rate of 2 L·min

-1

and voltage of 47 V

the predicted decolorization of 94.083% was achieved at 93.972% with a total cost of 0.0927 USD·m

-3

of treated effluent. At the optimum pH (7.5)

the zeta potential value (-4 mV) of the effluent during EC match with the one of iro

n Ⅲ hydroxide. The dye removal is ensured thanks to physical adsorption and flocculation. The results exposed in this work prove that the continuous electrocoagulation process could be successfully used for indigo dye removal at industrial scale.