Growth process and short chain alcohol separation performance of fluoride-containing NaY zeolite membrane
Separation Science and Engineering|Updated:2026-01-06
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Growth process and short chain alcohol separation performance of fluoride-containing NaY zeolite membrane
Growth process and short chain alcohol separation performance of fluoride-containing NaY zeolite membrane
中国化学工程学报(英文版)2021年29卷第1期 页码:154-159
Affiliations:
1. State-Province Joint Engineering Laboratory of Zeolite Membrane Materials, Institute of Advanced Materials, College of Chemistry and Chemical Engineering, Jiangxi Normal University,Nanchang,China,330022
2. Graduate School of Science and Technology for Innovation, Graduate School Science and Engineering, Yamaguchi University, Ube,Japan,755-8611
Author bio:
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中图分类号:
纸质出版:2021
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Xiaopan Chen, Meihua Zhu, Sitong Xiang, 等. Growth process and short chain alcohol separation performance of fluoride-containing NaY zeolite membrane[J]. 中国化学工程学报(英文版), 2021,29(1):154-159.
Xiaopan Chen, Meihua Zhu, Sitong Xiang, Tian Gui, Ting Wu, Yuqin Li, Na Hu, Izumi Kumakiri, Xiangshu Chen, Hidetoshi Kita. Growth process and short chain alcohol separation performance of fluoride-containing NaY zeolite membrane[J]. Chinese Journal of Chemical Engineering, 2021, 29(1): 154-159.
Xiaopan Chen, Meihua Zhu, Sitong Xiang, 等. Growth process and short chain alcohol separation performance of fluoride-containing NaY zeolite membrane[J]. 中国化学工程学报(英文版), 2021,29(1):154-159.DOI:
Xiaopan Chen, Meihua Zhu, Sitong Xiang, Tian Gui, Ting Wu, Yuqin Li, Na Hu, Izumi Kumakiri, Xiangshu Chen, Hidetoshi Kita. Growth process and short chain alcohol separation performance of fluoride-containing NaY zeolite membrane[J]. Chinese Journal of Chemical Engineering, 2021, 29(1): 154-159.DOI:
Growth process and short chain alcohol separation performance of fluoride-containing NaY zeolite membrane
Growth process of the NaY zeolite membranes was investigated by fluoride-containing precursor synthesis gel. Compared with the fluoride-free precursor synthesis gel
the irregular NaY zeolite crystals were dissolved into amorphous by the fluoride-containing precursor synthesis gel initially
the amorphous contained the Y-type zeolite characteristic bands by the IR characterization. The fine square NaY zeolite crystals arose from the amorphous
which were accumulated and gradually grew into a dense NaY zeolite layer on the support surface after 6.5 h. Because the excessive NaY zeolites were dissolved by the strong alkaline and fluoride-containing precursor synthesis gel
there was plenty of amorphous on NaY zeolites layer for prolonging the crystallization time. The as-synthesized NaY zeolite membranes had a good separation performance and repeatability for separation of 10 wt% methanol (MeOH)/methyl methacrylate (MMA) mixture by pervaporation
the flux and separation factor were (1.27 ± 0.07) kg·m
-2
·h
-1
and (4900 ± 1500) at 323 K
respectively. Besides
the NaY zeolite membranes were applied to separate the other short chain alcohol from the various alcohol/orga
nic ester and alcohol/organic ether mixtures
the NaY zeolite membranes showed high short chain alcohol perm-selectivity.
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