Electrochemical oxidation of Rhodamine B with cerium and sodium dodecyl benzene sulfonate co-modified Ti/PbO2 electrodes: Preparation, characterization, optimization, application
Catalysis, Kinetics and Reaction Engineering|Updated:2026-01-06
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Electrochemical oxidation of Rhodamine B with cerium and sodium dodecyl benzene sulfonate co-modified Ti/PbO2 electrodes: Preparation, characterization, optimization, application
Electrochemical oxidation of Rhodamine B with cerium and sodium dodecyl benzene sulfonate co-modified Ti/PbO2 electrodes: Preparation, characterization, optimization, application
2. Key Laboratory of Porous Metal Materials, Shaanxi Institute for Materials Engineering, Northwest Institute for Non-ferrous Metal Research,Xi'an,China,710016
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纸质出版:2021
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Zhen Wei, Xuanqi Kang, Shangyuan Xu, 等. Electrochemical oxidation of Rhodamine B with cerium and sodium dodecyl benzene sulfonate co-modified Ti/PbO2 electrodes: Preparation, characterization, optimization, application[J]. 中国化学工程学报(英文版), 2021,32(4):191-202.
Electrochemical oxidation of Rhodamine B with cerium and sodium dodecyl benzene sulfonate co-modified Ti/PbO2 electrodes: Preparation, characterization, optimization, application
摘要
Abstract
Regulation of the electronic structure and interface property becomes a major strategy in the preparation of electro-catalyst. This paper reports the synthesis of cerium (Ce) and sodium dodecyl benzene sulfonate (SDBS) co-modified Ti/PbO
2
electrodes (Ti/PbO
2
-Ce-SDBS). Ce and SDBS could greatly change the electronic structure and interface property of PbO
2
. Ti/PbO
2
-Ce-SDBS exhibited excellent electrocatalytic activity and stability in Rhodamine B (RhB) electrocatalytic oxidation reaction. The improved electrocatalytic activity associates with the synergistic effect of electronic and interface factors. In the electrochemical degradation of RhB
the removal efficiencies of RhB and COD are about 0.880 and 0.694 respectively after the electrolysis of 220 min with Ti/PbO
2
-Ce-4-SDBS-40
which are higher than the contrast Ti/PbO
2
electrodes. In the meantime
the accelerated lifetime of Ti/PbO
2
-Ce-4-SDBS-40 is more than 6.2 times than that of Ti/PbO
2
.
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相关作者
Xiao Wei
Xuan Fang
Shuming Ma
Huaqiang He
Zhixin Wu
Silin Li
Shihao Zhang
Pei Nian
相关机构
State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, School of Chemistry and Chemical Engineering, Ningxia University
Research Institute of Natural Gas Technology, PetroChina Southwest Oil & Gasfield Company
Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University