) capture is still limited by high desorption energy consumption. Fixing CO
2
into carbonate is a safer and more permanent method. In this work
calcium oxide (CaO) is introduced to perform chemical desorption instead of thermal desorption on 1
8-diazabicyclo [5.4.0
]
undec-7-ene (DBU) aqueous solution after CO
2
absorption. The X-ray diffraction (XRD) patterns of solid products show the formation of calcite calcium carbonate (CaCO
3
)
which prove the feasibility of this method. The effects of reaction temperature
reaction time and Ca
2+
/CO
3
2-
molar ratios on the related reactions in CO
2
absorption-mineralization process and CaCO
3
precipitation are discussed
and purer CaCO
3
is obtained by ultrasonic treatment. The CaCO
3
content can be increased to 95.8% and the CO
2
desorption ratio can achieve 80% by 30 min ultrasonic dispersion treatment under the conditions (40 ℃
180 min
Ca
2+
/CO
3
2-
molar ratio = 1.0). After five cycles
DBU aqueous solution shows stable CO
2
absorption and mineralization ability. Fourier transform infrared spectroscopy (FT-IR) spectra of the reaction process also indicate the regeneration of the solvent. Compared with thermal desorption
this process is exothermic
almost without no additional heat.
关键词
Keywords
references
The trial reading is over, you can activate your VIP account to continue reading.
Influence of the Surface and Structural Characteristics of Activated Carbons on Adsorptive Removal of Halo-Olefinic Impurities from 1,1,1,3,3-Pentafluoropropane
Measurement and Correlation of Vapor-Liquid Equilibrium for Binary System 1,2-Epoxycyclohexane+1,2-Dichloroethane
Development of a capillary bundle evaporation advanced mathematical modeling for 1,2-propylene glycol-glycerin mixtures in porous media
Palladium-catalyzed dicarbonylation of 1,3-butadiene with bidentate phosphine ligands: A density functional theory study
Simple substituents make big differences in photophysical performances of 2,1,3-benzothiadizole-conjugated spiropyrans
相关作者
Bo Zhang
Chuang Zhang
MingquanWei
周彩荣
王海峰
石晓华
蒋登高
Bingbing Li
相关机构
Research Institute of Industrial Catalysis, Zhejiang University of Technology
School of Chemical Engineering & Energy, Zhengzhou University
Tianjin Key Laboratory of Chemical Process Safety and Equipment Technology
College of New Energy & Materials, Northeast Petroleum University
School of Chemical Engineering and Technology, Tianjin University