Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTixFe1-xO3
Energy, Resources and Environmental Technology|Updated:2026-01-06
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Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTixFe1-xO3
Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTixFe1-xO3
中国化学工程学报(英文版)2019年27卷第8期 页码:1939-1944
Affiliations:
1. College of Chemistry & Chemical Engineering, Northeast Petroleum University,Daqing,China,163318
2. Provincial Key Laboratory of Oil & Gas Chemical Technology,Daqing,China,163318
3. Daqing Petrochemical Research Center, PetroChina,Daqing,China,163000
Author bio:
Funds:
DOI:
中图分类号:
纸质出版:2019
Accepted:
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Haiying Wang, Hongjing Han, Enhao Sun, 等. Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTixFe1-xO3[J]. 中国化学工程学报(英文版), 2019,27(8):1939-1944.
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Haiying Wang, Hongjing Han, Enhao Sun, 等. Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTixFe1-xO3[J]. 中国化学工程学报(英文版), 2019,27(8):1939-1944.DOI:
FeDOI:
Production of aryl oxygen-containing compounds from catalytic pyrolysis of bagasse lignin over LaTixFe1-xO3
named production of aryl oxygen-containing compounds from the catalytic pyrolysis of bagasse lignin (BL) over perovskite oxide
was proposed. A series of LaTi
x
Fe
1-
x
O
3
(LTF-
x
) samples were prepared by the solid state reaction method. The crystal phase and morphology of LTF-
x
were characterized by XRD and SEM respectively. Catalytic pyrolysis performance of LTF-
x
was performed by TG-DTG and the distribution patterns of gaseous
liquid and solid products from BL was investigated using a fixed-bed micro-reactor. The optimal reaction conditions were determined:the pyrolysis temperature was 600℃
the mass ratio of
m
BL
:
m
LTF-0.2
was 3:1
the velocity of carrier gas was 100 ml·min
-1
. The gaseous products were mainly composed of CO
2
CO
CH
4
and C
n
H
m
(
n
=2-4
m
=2
n
+ 2 or
m
=2
n
). The main aryl oxygen-containing compounds in liquid products were phenolics
guaiacols
syringols and phenylates
the rest were
benzenes
furans
esters and carboxylic acid. The total contents of aryl oxygencontaining compounds were from 62% up to more than 72% under the action of the perovskite. Moreover
the LTF-0.2 sample had nice regenerability.
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