after experimentalmeasurement of interfacial tension
different models includingmono-exponential decay
dynamic adsorptionmodels and empirical equation are used to correlate this time-dependent behavior of interfacial tension (IFT). During the modeling approach
the induction
adsorption
equilibrium
and mesoequilibrium times as well as diffusivity of surface active components known as natural surfactant including asphaltene and resin from crude oil to the interface are obtained. In addition
the surface excess concentration of surface active components at the interface and Gibbs adsorption isothermare utilized to analyze the measured dynamic IFTs. Finally
the mechanisms of crude oil/aqueous solution IFT including (a) the activity of surfaceactive components and (b) surface excess concentration of them at fluid/fluid interface are proposed and discussed in details.
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Keywords
references
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相关作者
Guo Yan
Hou Tuanyuan
Wang Yongjin
Chang Liping
Wang Jiancheng
Liao Junjie
Lu Tangzheng
Feng Jiayi
相关机构
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology
College of Chemistry and Chemical Engineering, Xinjiang Normal University
Key Laboratory of Coal Science and Technology, Ministry of Education, Taiyuan University of Technology
College of Chemistry and Chemical Engineering, Taiyuan University of Technology
School of Chemical Engineering and Technology, Tianjin University