A mathematic model is developed for the perovskite-type mixed ionic-electronic conducting (MIEC) membrane
which makes it possible to simulate the process of oxygen separation in the U-shaped Ba
0.5
Sr
0.5
Co
0.8
Fe
0.2
O
3-δ
hollow-fiber membrane. The model correlates the oxygen permeation flux to the measurable variables. The trends of calculated results for purge operation coincide well with the experimental data
therefore the model is considerable for flux prediction under vacuum operation. Higher oxygen separation efficiency can be achieved with vacuum operation than purge operation. Parameter study with vacuum operation reveals that oxygen permeation flux increases with higher vacuum levels
and vacuum pressure of around 1.013×10
3
Pa is the optimal. Also
vacuum operation on the lumen side is much more efficient to achieve higher oxygen permeation flux compared with compression mode on the shell side.
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references
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Experiments and model development of p-nitrochlorobenzene and naphthalene purification in a continuous tower melting crystallizer
相关作者
Zhang Guodong
Xu Songling
Zeng Xingye
Jiang Yanbin
Zhou Rujin
Lai Zhiping
Guangzhong Cao
Kaichen Zhang
相关机构
School of Chemical Engineering, Guangdong University of Petrochemical Technology
Center of Excellence for Renewable Energy and Storage Technologies, Division of Physical Science and Engineering, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia
Key Laboratory of Precision and Intelligent Chemistry, School of Chemistry and Materials Science, University of Science and Technology of China
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University
Chambroad Chemical Industry Research Institute Co. Ltd.