Multiple linear equation of pore structure and coal-oxygen diffusion on low temperature oxidation process of lignite
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Multiple linear equation of pore structure and coal-oxygen diffusion on low temperature oxidation process of lignite
Multiple linear equation of pore structure and coal-oxygen diffusion on low temperature oxidation process of lignite
中国化学工程学报(英文版)2016年第6期 页码:818-823
Affiliations:
1. School of Chemical Engineering and Technology, China University of Mining & Technology,Xuzhou,China,221116
2. 2 Key Laboratory of Gas and Fire Control for Coal Mines, China University of Mining & Technology,Xuzhou,China,221116
Author bio:
Funds:
Supported by the National Natural Science Foundation of China (51204179, 51204182) and the Natural Science Foundation of Jiangsu Province, China (BK20141242).
DOI:
中图分类号:
纸质出版:2016
Accepted:
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Xianliang Meng, Mingqiang Gao, Ruizhi Chu, 等. Multiple linear equation of pore structure and coal-oxygen diffusion on low temperature oxidation process of lignite[J]. 中国化学工程学报(英文版), 2016,(6):818-823.
Xianliang Meng, Mingqiang Gao, Ruizhi Chu, et al. Multiple linear equation of pore structure and coal-oxygen diffusion on low temperature oxidation process of lignite[J]. Chinese Journal of Chemical Engineering, 2016, (6): 818-823.
Xianliang Meng, Mingqiang Gao, Ruizhi Chu, 等. Multiple linear equation of pore structure and coal-oxygen diffusion on low temperature oxidation process of lignite[J]. 中国化学工程学报(英文版), 2016,(6):818-823.DOI:
Xianliang Meng, Mingqiang Gao, Ruizhi Chu, et al. Multiple linear equation of pore structure and coal-oxygen diffusion on low temperature oxidation process of lignite[J]. Chinese Journal of Chemical Engineering, 2016, (6): 818-823.DOI:
Multiple linear equation of pore structure and coal-oxygen diffusion on low temperature oxidation process of lignite
摘要
Abstract
This work aimed at studying the feasibility of calculating the coal-oxygen diffusion properties during the low temperature oxidation process of lignite so as to predict its spontaneous combustion process. Coal samples were oxidized in air ambient under different temperatures. Scanning Electron Microscope was used to indicate the surface morphology changes of oxidization. Then
based on fractal theory and flow characteristics
the fractal dimension of gas diffusion in the pore ways was calculated under different temperature. Considering pore size distribution
connectivity distribution and Fick diffusion mechanisms
the relationship between the gas diffusivity change with pore area fractal dimension and porosity was investigated
and multiple linear equation of the coal-oxygen diffusion coefficients and pore parameters was obtained. Comparison between the experimental data and model prediction verifies the validity of the model. The research provides a theoretical basis for the prediction model of coal-oxygen diffusion law.
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