on the chemical and mechanical properties of iron based FT catalyst was studied in this work. The samples were characterized using XRD
BET
TEM
FT-IR
and H2-TPR
respectively. The attrition resistance and the FT activity were tested. Si-8-Si-15 catalysts prepared with 8-15 nm silica sol show good attrition resistance (attrition loss4%)
especially Si-13 with an attrition loss of 1.89%. Hematite appeared in XRD patterns when silica sol above 15 nm is used. TEM micrographs show that no obvious SiO
2
particles appear when silica sol particle with size less than 8 nm was used
but SiO
2
particles coated with small ferrihydrite particles appear when silica sol above 8 nm was used. Si-O-Si vibration peak in FT-IR spectra increases with increasing silica sol size. Samples prepared with silica sol show good stability of FT reactions
and the average molecular weight of FT products increases with the increase of SiO
2
particle.
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references
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Modeling analysis of cobalt-based Fischer-Tropsch catalyst particles
Microchannel reactors for Fischer-Tropsch synthesis: Experimental investigation and mathematical modeling
Design and control of fraction cutting for the separation of mixed alcohols from the Fischer-Tropsch aqueous by-products
Manipulating metal-support interactions of metal catalysts for Fischer-Tropsch synthesis
Modeling and optimization of industrial Fischer-Tropsch synthesis with the slurry bubble column reactor and iron-based catalyst
相关作者
Yongwang Li
Yong Yang
Gang Wang
Huashuai Wu
Chaopeng Hou
Shuandi Hou
Tao Yang
Xiaojin Tang
相关机构
College of Chemical Engineering and Technology, Taiyuan University of Technology
National Energy Research & Development Center for Coal to Liquid Fuels, Synfuels China Company, Limited
SINOPEC Research Institute of Petroleum Processing Co., Ltd.
School of Chemical Engineering and Technology, State Key Laboratory of Chemical Engineering, Chemical Engineering Research Center, Tianjin University
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), State Key Laboratory of Chemical Engineering, Tianjin Key Laboratory of Applied Catalysis Science and Technology, School of Chemical Engineering and Technology, Tianjin University