Deviation of Carbon Dioxide-Water Gas-Liquid Balance from Thermodynamic Equilibrium in Turbulence Ⅰ: Experiment and Correlation

张珍禛; 钱智; 徐联滨; 吴彩艳; 郭锴

Your Location：

Home >

Browse articles >

Deviation of Carbon Dioxide-Water Gas-Liquid Balance from Thermodynamic Equilibrium in Turbulence Ⅰ: Experiment and Correlation

化工热力学 | Updated：2026-01-06

- Deviation of Carbon Dioxide-Water Gas-Liquid Balance from Thermodynamic Equilibrium in Turbulence Ⅰ: Experiment and Correlation
- Deviation of Carbon Dioxide-Water Gas-Liquid Balance from Thermodynamic Equilibrium in Turbulence Ⅰ: Experiment and Correlation
- 中国化学工程学报（英文版） 2013年21卷第7期页码：770-7751004-954160540-6
- Affiliations：
  
  2 University of Chinese Academy of Sciences,Beijing,China,100049
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：2013
- Accepted：
Scan QR Code
张珍禛, 钱智, 徐联滨, 等. Deviation of Carbon Dioxide-Water Gas-Liquid Balance from Thermodynamic Equilibrium in Turbulence Ⅰ: Experiment and Correlation[J]. 中国化学工程学报（英文版）, 2013,21(7):770-7751004-954160540-6.

ZHANG Zhenzhen, QIAN Zhi, XU Lianbin, WU Caiyan, GUO Kai . Deviation of Carbon Dioxide-Water Gas-Liquid Balance from Thermodynamic Equilibrium in Turbulence Ⅰ: Experiment and Correlation[J]. Chin.J.Chem.Eng., 2013, 21(7): 770-775.
张珍禛, 钱智, 徐联滨, 等. Deviation of Carbon Dioxide-Water Gas-Liquid Balance from Thermodynamic Equilibrium in Turbulence Ⅰ: Experiment and Correlation[J]. 中国化学工程学报（英文版）, 2013,21(7):770-7751004-954160540-6. DOI：

ZHANG Zhenzhen, QIAN Zhi, XU Lianbin, WU Caiyan, GUO Kai . Deviation of Carbon Dioxide-Water Gas-Liquid Balance from Thermodynamic Equilibrium in Turbulence Ⅰ: Experiment and Correlation[J]. Chin.J.Chem.Eng., 2013, 21(7): 770-775. DOI：

摘要

Abstract

The carbon dioxide-water system was used to investigate the flowing gas-liquid metastable state. The experiment was carried out in a constant volume vessel with a horizontal circulation pipe and a peristaltic pump forced CO

saturated water to flow. The temperature and pressure were recorded. The results showed that some CO

escaped from the water in the flow process and the pressure increased

indicating that the gas-liquid equilibrium was broken. The amount of escaped CO

varied with flow speed and reached a limit in a few minutes

entitled dynamic equilibrium. Temperature and liquid movement played the same important role in breaking the phase equilibrium. Under the experimental conditions

the ratio of the excessive carbon dioxide in the gas phase to its thermodynamic equilibrium amount in the liquid could achieve 15%.

关键词

Keywords

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Mass transfer correlations for membrane gas-solvent contactors undergoing carbon dioxide desorption

CaO-stabilized tetragonal ZrO2 support for high-performance Ni—Fe alloy catalysts in dry reforming of methane

Imidazole-based porous organic polymers featuring hydrogen bond donors as environmentally friendly heterogeneous catalysts for efficient CO2 conversion

Thermodynamic feasibility of nickel and cerium oxides as versatile oxygen carriers in chemical looping reforming of methane-rich feedstocks

Thermal decomposition behavior and kinetics of magnesite under carbon dioxide atmosphere