Removal of Cu(Ⅱ) from Aqueous Solution Using a Novel Crosslinked Alumina-Chitosan Hybrid Adsorbent
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Removal of Cu(Ⅱ) from Aqueous Solution Using a Novel Crosslinked Alumina-Chitosan Hybrid Adsorbent
Removal of Cu(Ⅱ) from Aqueous Solution Using a Novel Crosslinked Alumina-Chitosan Hybrid Adsorbent
中国化学工程学报(英文版)2012年20卷第4期 页码:641-648
Affiliations:
1. College of Chemistry, Jilin University,Changchun,China,130026
2. College of Engineering and Architecture, Liaoning Technical University,Fuxin,China,123000
Author bio:
Funds:
Supported by the National Innovative Projects with Cooperation in terms of Production,Study and Research (OSR-05);the National Science and Technology Major Projects (2008ZX05018-005)
DOI:
中图分类号:
纸质出版:2012
Accepted:
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季桂娟, 包维维, 高桂梅, 等. Removal of Cu(Ⅱ) from Aqueous Solution Using a Novel Crosslinked Alumina-Chitosan Hybrid Adsorbent[J]. 中国化学工程学报(英文版), 2012,20(4):641-648.
JI Guijuan, BAO Weiwei, GAO Guimei, AN Baichao, ZOU Haifeng, GAN Shucai. Removal of Cu(Ⅱ) from Aqueous Solution Using a Novel Crosslinked Alumina-Chitosan Hybrid Adsorbent[J]. Chin.J.Chem.Eng., 2012, 20(4): 641-648.
季桂娟, 包维维, 高桂梅, 等. Removal of Cu(Ⅱ) from Aqueous Solution Using a Novel Crosslinked Alumina-Chitosan Hybrid Adsorbent[J]. 中国化学工程学报(英文版), 2012,20(4):641-648.DOI:
JI Guijuan, BAO Weiwei, GAO Guimei, AN Baichao, ZOU Haifeng, GAN Shucai. Removal of Cu(Ⅱ) from Aqueous Solution Using a Novel Crosslinked Alumina-Chitosan Hybrid Adsorbent[J]. Chin.J.Chem.Eng., 2012, 20(4): 641-648.DOI:
Removal of Cu(Ⅱ) from Aqueous Solution Using a Novel Crosslinked Alumina-Chitosan Hybrid Adsorbent
A novel biosorbent was developed by coating chitosan
a naturally and abundantly available biopolymer
on to activated alumina based on oil shale ash via crosslinking.The adsorbent was characterized by various techniques
such as Fourier transform infrared spectroscopy
scanning electron microscopy
thermogravimetric-differential thermal analysis
and X-ray photoelectron spectroscope.Batch isothermal equilibrium adsorption experiments were condcted to evaluate the adsorbent for the removal of Cu(Ⅱ) from wastewater.The effect of pH and agitation time on the adsorption capacity was also investigated
indicating that the optimum pH was 6.0.The equilibrium adsorption data were correlated with Langmuir and Freundlich models.The maximum monolayer adsorption capacity of chitosan coated alumina sorbent as obtained from Langmuir adsorption isotherm was found to be 315.46 mg·g
-1
for Cu(Ⅱ).The adsorbent loaded with Cu(Ⅱ) was readily regenerated using 0.1 mol·L
-1
sodium hydroxide solution.All these indicated that chitosan coated alumina adsorbent not only have high adsorption activity
but also had good stability in the wastewater treatment process.
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