Salt Effect on the Liquid-Liquid Equilibrium of(Water+Propionic Acid+Cyclohexanol)System at T=(298.2, 303.2, 308.2)K
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Salt Effect on the Liquid-Liquid Equilibrium of(Water+Propionic Acid+Cyclohexanol)System at T=(298.2, 303.2, 308.2)K
Salt Effect on the Liquid-Liquid Equilibrium of(Water+Propionic Acid+Cyclohexanol)System at T=(298.2, 303.2, 308.2)K
中国化学工程学报(英文版)2011年19卷第4期 页码:565-569
Affiliations:
Department of Chemistry, Faculty of Science, University of Guilan, P. O. Box:19141, Rasht,Iran
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纸质出版:2011
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Bahram Ghalami-Choobar, Ali Ghanadzadeh, Shahram Kousarimehr. Salt Effect on the Liquid-Liquid Equilibrium of(Water+Propionic Acid+Cyclohexanol)System at T=(298.2, 303.2, 308.2)K[J]. 中国化学工程学报(英文版), 2011,19(4):565-569.
Bahram Ghalami-Choobar, Ali Ghanadzadeh, Shahram Kousarimehr. Salt Effect on the Liquid-Liquid Equilibrium of(Water+Propionic Acid+Cyclohexanol)System at T=(298.2, 303.2, 308.2)K[J]. 中国化学工程学报(英文版), 2011,19(4):565-569.DOI:
Effects of salt and temperature on the liquid phase equilibrium of the(water+propionic acid+cyclohexanol) system were investigated.The liquid-liquid equilibrium data in the presence of KCl for various salt ionic strength of 0.5
1.0
1.5
2.0
and 2.5 mol·dm
3
and in absence of the salt at
T
=(298.2
303.2
and 308.2)K were determined.The experimental results were correlated based on the Othmer-Tobias equation and Pitzer ion-interaction model.Thermodynamic properties such as distribution coefficients and activity coefficients of propionic acid in water+cyclohexanol were determined.In addition
the separation factor
S
of the chosen solvent was obtained for the investigated system.
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