Effect of the Para-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation

杨刚; 秦冬玲; 高宏飞; 徐南平

Your Location：

Home >

Browse articles >

Effect of the Para-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation

评述 | Updated：2026-01-06

- Effect of the Para-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation
- Effect of the Para-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation
- 中国化学工程学报（英文版） 2011年19卷第1期页码：169-172
- Affiliations：
  
  State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology,Nanjing,China,10009
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：2011
- Accepted：
Scan QR Code
杨刚, 秦冬玲, 高宏飞, 等. Effect of the Para-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation[J]. 中国化学工程学报（英文版）, 2011,19(1):169-172.

-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation[J]. Chinese Journal of Chemical Engineering, 2011, 19(1): 169-172.
杨刚, 秦冬玲, 高宏飞, 等. Effect of the Para-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation[J]. 中国化学工程学报（英文版）, 2011,19(1):169-172. DOI：

-substituent of the Tridentate Pyridine-based Ru(Ⅱ) Complex upon the Catalytic Activity in Transfer Hydrogenation[J]. Chinese Journal of Chemical Engineering, 2011, 19(1): 169-172. DOI：

摘要

Abstract

Three stable 4-substituted pyridine-based ruthenium(Ⅱ)complexes[RuCl

(PPh

]

(L=4-R-2

6-bis (diethylaminomethylene)pyridine

R=Br

H or allyloxy)were synthesized.The catalytic activities of the complexes toward transfer hydrogenation from alcohols to ketones were investigated.The electronic effects of the para-substituent in the pyridyl ring were probed and we found that the electron-donating group increased the catalytic activity.The result suggests that an electron-donating group is probably preferential for linking the catalytic ruthenium complex and the chemically inert supporting molecules such as a carbosilane dendrimer.

关键词

Keywords

references

浏览量

977

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Imidazole-based porous organic polymers featuring hydrogen bond donors as environmentally friendly heterogeneous catalysts for efficient CO2 conversion

Impact of sugar type on thiophene hydrodesulfurization performance of three-dimensional porous CoMo bulk catalysts prepared via the sugar foaming method

Kinetic and process analysis of continuous catalytic distillation for high-purity propylene glycol monomethyl ether acetate production

Highly efficient cleavage of CO bonds in diphenyl ether over Ni-S2O82-/ZrO2 solid super acid catalysts

Synergistic effect of Co0 with Cu11In9 intermetallic compound enhancing catalytic performance of CO2 hydrogenation to methanol