Vapour-Liquid Equilibrium with a New Ebulliometer:Ester+Alcohol System at 0.5 Mpa

P. Susial; A. Sosa-Rosario; R. Rios-Santana

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Vapour-Liquid Equilibrium with a New Ebulliometer:Ester+Alcohol System at 0.5 Mpa

Updated：2026-01-06

- Vapour-Liquid Equilibrium with a New Ebulliometer:Ester+Alcohol System at 0.5 Mpa
- Vapour-Liquid Equilibrium with a New Ebulliometer:Ester+Alcohol System at 0.5 Mpa
- 中国化学工程学报（英文版） 2010年18卷第6期页码：1000-1007
- Affiliations：
  
  School of Industrial Engineering, University of Las Palmas de Gran Canaria, Canary Islands,Spain
- Author bio：
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- 纸质出版：2010
- Accepted：
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P. Susial, A. Sosa-Rosario, R. Rios-Santana. Vapour-Liquid Equilibrium with a New Ebulliometer:Ester+Alcohol System at 0.5 Mpa[J]. 中国化学工程学报（英文版）, 2010,18(6):1000-1007.

P. Susial, A. Sosa-Rosario, R. Rios-Santana. Vapour-Liquid Equilibrium with a New Ebulliometer:Ester+Alcohol System at 0.5 MPa[J]. , 2010, 18(6): 1000-1007.
P. Susial, A. Sosa-Rosario, R. Rios-Santana. Vapour-Liquid Equilibrium with a New Ebulliometer:Ester+Alcohol System at 0.5 Mpa[J]. 中国化学工程学报（英文版）, 2010,18(6):1000-1007. DOI：

P. Susial, A. Sosa-Rosario, R. Rios-Santana. Vapour-Liquid Equilibrium with a New Ebulliometer:Ester+Alcohol System at 0.5 MPa[J]. , 2010, 18(6): 1000-1007. DOI：

摘要

Abstract

A new dynamic ebulliometer is used to determine vapor-liquid equilibrium(VLE) data experimentally. In the equipment

both phases are recirculated. Its operation is a consequence of the Cotrell pump effect produced when the mixture is heated in a double-walled inverted vessel. The reliability of the apparatus is tested with the mixtures studied previously by various authors. VLE data for the binary systems of methyl acetate + methanol and the methyl acetate + ethanol at 0.5 MPa are determined. The experimental data are confirmed with the point-to-point test of van Ness

applying the Fortran program of Frendslund

et al

. In addition

the experimental results are compared with the UNIFAC(including different versions) and ASOG prediction models.

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