Epoxidation of Unsaturated Fatty Acid Methyl Esters in the Presence of SO<sub>3</sub>H-functional Brφnsted Acidic Ionic Liquid as Catalyst

蔡双飞; 王利生

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Epoxidation of Unsaturated Fatty Acid Methyl Esters in the Presence of SO₃H-functional Brφnsted Acidic Ionic Liquid as Catalyst

Updated：2026-01-06

- Epoxidation of Unsaturated Fatty Acid Methyl Esters in the Presence of SO₃H-functional Brφnsted Acidic Ionic Liquid as Catalyst
- Epoxidation of Unsaturated Fatty Acid Methyl Esters in the Presence of SO₃H-functional Brφnsted Acidic Ionic Liquid as Catalyst
- 中国化学工程学报（英文版） 2011年19卷第1期页码：57-63
- Affiliations：
  
  School of Chemical Engineering and Environment, Beijing Institute of Technology,Beijing,China,100081
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：2011
- Accepted：
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蔡双飞, 王利生. Epoxidation of Unsaturated Fatty Acid Methyl Esters in the Presence of SO₃H-functional Brφnsted Acidic Ionic Liquid as Catalyst[J]. 中国化学工程学报（英文版）, 2011,19(1):57-63.

H-functional Brφnsted Acidic Ionic Liquid as Catalyst[J]. , 2011, 19(1): 57-63.
蔡双飞, 王利生. Epoxidation of Unsaturated Fatty Acid Methyl Esters in the Presence of SO₃H-functional Brφnsted Acidic Ionic Liquid as Catalyst[J]. 中国化学工程学报（英文版）, 2011,19(1):57-63. DOI：

H-functional Brφnsted Acidic Ionic Liquid as Catalyst[J]. , 2011, 19(1): 57-63. DOI：

摘要

Abstract

The epoxidation of unsaturated fatty acid methyl esters(FAMEs)by peroxyacetic acid generated

in situ

from hydrogen peroxide and acetic acid was studied in the presence of SO

H-functional Brnsted acidic ionic liquid (IL)[C

HMIM

]

[HSO

]

as catalyst.The effects of hydrogen peroxide/ethylenic unsaturation ratio

acetic acid concentration

IL concentration

recycling of the IL catalyst

and temperature on the conversion to oxirane were studied.The kinetics and thermodynamics of unsaturated FAMEs epoxidation and the kinetics of oxirane cleavage of the epoxidized FAMEs by acetic acid were also studied.The conversion of ethylenic unsaturation group to oxirane

the reaction rate of the conversion to oxirane

and the rate of hydrolysis(oxirane cleavage)were higher by using the IL catalyst.

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Epoxidation of Unsaturated Fatty Acid Methyl Esters in the Presence of SO3H-functional Brφnsted Acidic Ionic Liquid as Catalyst

Epoxidation of Unsaturated Fatty Acid Methyl Esters in the Presence of SO3H-functional Brφnsted Acidic Ionic Liquid as Catalyst

DOI：

摘要

Abstract

关键词

Keywords

references

Epoxidation of Unsaturated Fatty Acid Methyl Esters in the Presence of SO₃H-functional Brφnsted Acidic Ionic Liquid as Catalyst

Epoxidation of Unsaturated Fatty Acid Methyl Esters in the Presence of SO₃H-functional Brφnsted Acidic Ionic Liquid as Catalyst