Adsorption Behavior of Methyl Orange onto Modified Ultrafine Coal Powder
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Adsorption Behavior of Methyl Orange onto Modified Ultrafine Coal Powder
Adsorption Behavior of Methyl Orange onto Modified Ultrafine Coal Powder
中国化学工程学报(英文版)2009年17卷第6期 页码:942-948
Affiliations:
1. College of Geology and Environment, Xi'an University of Science & Technology,Xi'an,China,710054
2. College of Chemistry and Chemical Engineering, Xi'an University of Science & Technology,Xi'an,China,710054
Author bio:
Funds:
Supported by the National Science Foundation for Post Doctoral Scientists of China (20070411124);Scientific and Technological Key Project of Shaanxi Province (2006k07-G19);Industrialization Project of Shaanxi Provincial Department of Education (06JC11)
The adsorption of methyl orange onto ultrafine coal powder(UCP) and modified ultrafine coal powder(MUCP) from aqueous solutions were studied
in which the influence of contact time
dosage
temperature
pH
and methyl orange concentration in the solution were investigated.The adsorption kinetics of methyl orange by UCP and MUCP can be described by the Lagergren first-order and pseudo second-order kinetic models
respectively.The adsorption isotherms of methyl orange onto MUCP at 303
313 and 323 K follow the Freundlich and Langmuir isotherm equation.Values of Δ
G
0
for methyl orange adsorption onto MUCP are -22.55
-23.10 and -23.79 kJ·mol
-1
at 303
313
and 323 K
respectively.The values of Δ
H
0
and Δ
S
0
are Δ3.74 kJ·mol
-1
and 61.99 J·mol
-1
respectively.The adsorption process is spontaneous and exothermic.
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Keywords
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相关作者
Chunmei Zhu
Liting Zhang
Chenyuan Cui
Xin Lian
Long Qu
Bai He
Guoyuan Yuan
Jian Feng
相关机构
School of Chemistry and Chemical Engineering, Chongqing University of Science and Technology
Research Center of Smart Environmental Analysis, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences
Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, Bangi
Department of Mechanical and Aerospace Engineering, University at Buffalo
Department of Chemical and Biomolecular Engineering, University of Connecticut, Storrs