Synthesis of Co Nanoparticles and Their Catalytic Effect on the Decomposition of Ammonium Perchlorate

段红珍; 蔺向阳; 刘冠鹏; 徐磊; 李凤生

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Synthesis of Co Nanoparticles and Their Catalytic Effect on the Decomposition of Ammonium Perchlorate

Updated：2026-01-06

- Synthesis of Co Nanoparticles and Their Catalytic Effect on the Decomposition of Ammonium Perchlorate
- Synthesis of Co Nanoparticles and Their Catalytic Effect on the Decomposition of Ammonium Perchlorate
- 中国化学工程学报（英文版） 2008年16卷第2期页码：325-328
- Affiliations：
  
  1. School of Chemical Engineering, Nanjing University of Science and Technology,Nanjing,China,210094
  2. Department of Chemistry, School of Science, North University of China,Taiyuan,China,030051
- Author bio：
- Funds：
- DOI：
  中图分类号：
- 纸质出版：2008
- Accepted：
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段红珍, 蔺向阳, 刘冠鹏, 等. Synthesis of Co Nanoparticles and Their Catalytic Effect on the Decomposition of Ammonium Perchlorate[J]. 中国化学工程学报（英文版）, 2008,16(2):325-328.

DUAN Hongzhen, LIN Xiangyang, LIU Guanpeng, XU Lei, LI Fengsheng. Synthesis of Co Nanoparticles and Their Catalytic Effect on the Decomposition of Ammonium Perchlorate[J]. , 2008, 16(2): 325-328.
段红珍, 蔺向阳, 刘冠鹏, 等. Synthesis of Co Nanoparticles and Their Catalytic Effect on the Decomposition of Ammonium Perchlorate[J]. 中国化学工程学报（英文版）, 2008,16(2):325-328. DOI：

DUAN Hongzhen, LIN Xiangyang, LIU Guanpeng, XU Lei, LI Fengsheng. Synthesis of Co Nanoparticles and Their Catalytic Effect on the Decomposition of Ammonium Perchlorate[J]. , 2008, 16(2): 325-328. DOI：

摘要

Abstract

The monodispersed Co nanoparticles were successfully prepared by means of hydrogen plasma method in inert atmosphere.The particle size

specific surface area

crystal structure and morphology of the samples were characterized by transmission electron microscopy(TEM)

BET equation

X-ray diffraction(XRD)

and the corre-sponding selected area electron diffraction(SAED).The catalytic effect of Co nanoparticles on the decomposition of ammonium perchlorate(AP)was investigated by differential thermal analyzer(DTA).Compared with the ther-mal decomposition of pure AP

the addition of Co nanoparticles(2%-10%

by mass)decreases the decomposition temperature of AP by 145.01-155.72℃.Compared with Co

nanoparticles and microsized Co particles

the catalytic effect of Co nanoparticles for AP is stronger.Such effect is attributed to the large specific surface area and its interaction of Co with decomposition intermediate gases.The present work provides useful information for the application of Co nanoparticles in the AP-based propellant.

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