Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins
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Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins
Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins
中国化学工程学报(英文版)2008年16卷第3期 页码:394-400
Affiliations:
State Key Laboratory of Heavy Oil Processing, College of Chemistry & Chemical Engineering, China University of Petroleum,Dongying,China,257061
Author bio:
Funds:
DOI:
中图分类号:
纸质出版:2008
Accepted:
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田华, 李春义, 杨朝合, 等. Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins[J]. 中国化学工程学报(英文版), 2008,16(3):394-400.
TIAN Hua, LI Chunyi, YANG Chaohe, SHAN Honghong. Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins[J]. , 2008, 16(3): 394-400.
田华, 李春义, 杨朝合, 等. Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins[J]. 中国化学工程学报(英文版), 2008,16(3):394-400.DOI:
TIAN Hua, LI Chunyi, YANG Chaohe, SHAN Honghong. Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins[J]. , 2008, 16(3): 394-400.DOI:
Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins
Since the production cost of biodiesel is now the main hurdle limiting their applicability in some areas
catalytic cracking reactions represent an alternative route to utilization of vegetable oils and animal fats. Hence
catalytic transformation of oils and fats was carried out in a laboratory-scale two-stage riser fluid catalytic cracking (TSRFCC) unit in this work. The results show that oils and fats can be used as FCC feed singly or co-feeding with vacuum gas oil (VGO)
which can give high yield (by mass)of liquefied petroleum gas (LPG)
C
2
-C
4
olefins
for example 45% LPG
47% C
2
-C
4
olefins
and 77.6% total liquid yield produced with palm oil cracking. Co-feeding with VGO gives a high yield of LPG (39.1%) and propylene (18.1%). And oxygen element content is very low (about 0.5%) in liquid products
hence
oxygen is removed in the form of H
2
O
CO and CO
2
. At the same time
high concentration of aromatics (C
7
-C
9
aromatics predominantly) in the gasoline fraction is obtained after TSRFCC reaction of palm oil
as a result of large amount of hydrogen-transfer
cyclization and aromatization reactions. Additionally
most of properties of produced gasoline and diesel oil fuel meet the requirements of national standards
containing little sulfur. So TSRFCC technology is thought to be an alternative processing technology leading to production of clean fuels and light olefins.
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相关机构
Department of Material Science and Engineering, School of Molecular Science & Engineering, Vidyasirimedhi Institute of Science and Technology, Wangchan
Biomass Energy Research Laboratory, Center of Excellence on Alternative Energy, Research and Development Institution, Sakon Nakhon Rajabhat University, Mueang District, Sakon Nakhon
Innovation in Chemistry for Community Research Unit, Faculty of Science and Technology, Sakon Nakhon Rajabhat University, Mueang District, Sakon Nakhon
Program of Chemistry, Faculty of Science and Technology, Sakon Nakhon Rajabhat University, Mueang District, Sakon Nakhon
Appropriated Technology Center, Faculty of Science and Technology, Sakon Nakhon Rajabhat University, Mueang District, Sakon Nakhon