Synthesis of Substituted <i>μ</i>-Oxo-bis[tetra-phenyl porphyrinatoiron] Compounds from Free Base Porphyrins by a One-pot Method

佘远斌; 冯连顺; 王爱欣; 李修艳

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Synthesis of Substituted μ-Oxo-bis[tetra-phenyl porphyrinatoiron] Compounds from Free Base Porphyrins by a One-pot Method

Updated：2026-01-06

- Synthesis of Substituted μ-Oxo-bis[tetra-phenyl porphyrinatoiron] Compounds from Free Base Porphyrins by a One-pot Method
- Synthesis of Substituted μ-Oxo-bis[tetra-phenyl porphyrinatoiron] Compounds from Free Base Porphyrins by a One-pot Method
- 中国化学工程学报（英文版） 2008年16卷第3期页码：369-372
- Affiliations：
  
  Institute of Green Chemistry and Fine Chemicals, Beijing University of Technology,Beijing,China,100022
- Author bio：
- Funds：
  
  Supported the National Natural Science Foundation of China (20776003,20576005);the Key Project of Natural Science Foundation of Beijing (2061001)
- DOI：
  中图分类号：
- 纸质出版：2008
- Accepted：
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佘远斌, 冯连顺, 王爱欣, 等. Synthesis of Substituted μ-Oxo-bis[tetra-phenyl porphyrinatoiron] Compounds from Free Base Porphyrins by a One-pot Method[J]. 中国化学工程学报（英文版）, 2008,16(3):369-372.

-Oxo-bis[tetra-phenyl porphyrinatoiron] Compounds from Free Base Porphyrins by a One-pot Method[J]. , 2008, 16(3): 369-372.
佘远斌, 冯连顺, 王爱欣, 等. Synthesis of Substituted μ-Oxo-bis[tetra-phenyl porphyrinatoiron] Compounds from Free Base Porphyrins by a One-pot Method[J]. 中国化学工程学报（英文版）, 2008,16(3):369-372. DOI：

-Oxo-bis[tetra-phenyl porphyrinatoiron] Compounds from Free Base Porphyrins by a One-pot Method[J]. , 2008, 16(3): 369-372. DOI：

摘要

Abstract

A novel method for synthesis of substitutedμ-oxo-bis[tetraphenyl porphyrinatoiron

]

compounds([TRPPFe

]

O) based on the reaction among free base porphyrins(TRPPH

)

FeSO

·7H

O and H

O in one pot was proposed and investigated.Four kinds of[TRPPFe

]

O were synthesized by this novel synthetic method

and their structures were characterized by elemental analysis

infrared spectra and UV-vis spectroscopy.The reaction conditions

including the effect of different iron salts on the formation of[TRPPFe

]

the reaction time between FeSO

·7H

O and TRPPH

the molar ratio of FeSO

·7H

O/TRPPH

as well as the volume ratio of H

O/DMF

were investigated.The [TRPPFe

]

O yield of 93%-98%could be obtained under the following optimal conditions:the reaction time of FeSO

·7H

O with TRPPH

was about 10 h

the molar ratio of FeSO

·7H

O/TRPPH

about 5:1

and the volume ratio of H

O/DMF exceeded 2:1.Further research indicated that only TRPPFeCl were formed once FeSO

·7H

O was replaced by FeCl

·4H

the reason of which might be that halogen ions in iron salts interfered the formation of [TRPPFe

]

suggesting that halogen ions should be avoided in this novel synthetic method.

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Synthesis of Substituted μ-Oxo-bis[tetra-phenyl porphyrinatoiron] Compounds from Free Base Porphyrins by a One-pot Method

Synthesis of Substituted μ-Oxo-bis[tetra-phenyl porphyrinatoiron] Compounds from Free Base Porphyrins by a One-pot Method

DOI：

摘要

Abstract

关键词

Keywords

references